BACKGROUND: 5-hydroxymethylfurfural (5-HMF), the major by-product in hydrolyzates from lignocelluloses and algal biomass, is known as an inhibitor of several microorganisms as well as a promising precursor for biorefinery. In this study, the feasibility of 5-HMF sequestration was investigated using granular activated carbon (GAC) as the adsorbent. RESULTS: Equilibria for the 5-HMF adsorption onto GAC were derived. Positive isosteric heat values showed the reaction was exothermic and favored at low temperature. The pseudo-second order dynamics and the estimated activation energy, 227.4 kJ mol-1, implied that the removal mechanism would be chemical adsorption. The adsorption was not interfered with by the presence of sugar and sugar compounds were not adsorbed onto GAC. CONCLUSION: Batch and column tests on dilute acid hydrolyzate of red algal biomass showed that GAC adsorption would be a feasible option for sequestration of 5-HMF in hydrolyzate for the biofuel and biorefinery industries.
Bibliographical notePublisher Copyright:
© 2016 Society of Chemical Industry.
All Science Journal Classification (ASJC) codes
- Chemical Engineering(all)
- Renewable Energy, Sustainability and the Environment
- Fuel Technology
- Waste Management and Disposal
- Organic Chemistry
- Inorganic Chemistry