Layered black phosphorus as a reducing agent-decoration with group 10 elements

Jan Plutnar; Zdeněk Sofer; Martin Pumera

doi:10.1039/d0ra06884e

Layered black phosphorus as a reducing agent-decoration with group 10 elements

Jan Plutnar, Zdeněk Sofer, Martin Pumera

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Black phosphorus is prone to surface oxidation under ambient conditions. This attribute is often seen as a negative property of this interesting material. However, its proneness to oxidation-thus the reductive properties-can also be employed in modification of its surface and in preparation of composite materials. Here we describe the process of decoration of BP particles with nickel, palladium and platinum in form of a phosphide or in metallic form, respectively. The deposits have forms of films or nanoparticles and the reported method represents a general way of modifying the surface of black phosphorus with metals or their respective compounds for desired applications.

Original language	English
Pages (from-to)	36452-36458
Number of pages	7
Journal	RSC Advances
Volume	10
Issue number	60
DOIs	https://doi.org/10.1039/d0ra06884e
Publication status	Published - 2020 Oct 2

Bibliographical note

Funding Information:
† This work was supported by the project Advanced Functional Nanorobots (reg. no. CZ.02.1.01/0.0/0.0/15_003/0000444 nanced by the EFRR). ‡ Electronic supplementary information (ESI) available. See DOI: 10.1039/d0ra06884e

Funding Information:
This work was supported by the project Advanced Functional Nanorobots (Reg. No. CZ.02.1.01/0.0/0.0/15_003/0000444 nanced by the EFRR).

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)

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abstract = "Black phosphorus is prone to surface oxidation under ambient conditions. This attribute is often seen as a negative property of this interesting material. However, its proneness to oxidation-thus the reductive properties-can also be employed in modification of its surface and in preparation of composite materials. Here we describe the process of decoration of BP particles with nickel, palladium and platinum in form of a phosphide or in metallic form, respectively. The deposits have forms of films or nanoparticles and the reported method represents a general way of modifying the surface of black phosphorus with metals or their respective compounds for desired applications.",

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AU - Sofer, Zdeněk

AU - Pumera, Martin

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