Layered franckeite and teallite intrinsic heterostructures: Shear exfoliation and electrocatalysis

Rui Gusmão, Zdeněk Sofer, Jan Luxa, Martin Pumera

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Research into van der Waals heterostructures (vdWH) has been mostly focused on fabricating individually stacked atomically thin crystals in lab settings. Interestingly, vdWH materials are also readily available from the Earth's lithosphere. Franckeite is a naturally-occurring misfit-layered vdWH, composed of Pb, Sn, Sb, Fe, and S. Teallite differs from franckeite by not containing Sb. Herein, naturally occurring sulfosalt materials, franckeite and teallite, undergo liquid-phase shear exfoliation, being examined for their structural and chemical properties. Subsequently, these exfoliated materials and their bulk counterparts are applied in electrocatalytic energy reactions. The results show the shear exfoliated teallite is the optimum sulfosalt for the oxygen evolution and reduction reactions. Finally, the shear-exfoliated franckeite shows improved hydrogen evolution performance in a wide pH range when compared to the remaining materials. This work demonstrates the promising potential of misfit-layered vdWH and layered sulfosalts as electrocatalysts for energy related applications.

Original languageEnglish
Pages (from-to)16590-16599
Number of pages10
JournalJournal of Materials Chemistry A
Volume6
Issue number34
DOIs
Publication statusPublished - 2018 Jan 1

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Electrocatalysis
Heterojunctions
Electrocatalysts
Chemical properties
Structural properties
Hydrogen
Earth (planet)
Oxygen
Crystals
Liquids

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

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abstract = "Research into van der Waals heterostructures (vdWH) has been mostly focused on fabricating individually stacked atomically thin crystals in lab settings. Interestingly, vdWH materials are also readily available from the Earth's lithosphere. Franckeite is a naturally-occurring misfit-layered vdWH, composed of Pb, Sn, Sb, Fe, and S. Teallite differs from franckeite by not containing Sb. Herein, naturally occurring sulfosalt materials, franckeite and teallite, undergo liquid-phase shear exfoliation, being examined for their structural and chemical properties. Subsequently, these exfoliated materials and their bulk counterparts are applied in electrocatalytic energy reactions. The results show the shear exfoliated teallite is the optimum sulfosalt for the oxygen evolution and reduction reactions. Finally, the shear-exfoliated franckeite shows improved hydrogen evolution performance in a wide pH range when compared to the remaining materials. This work demonstrates the promising potential of misfit-layered vdWH and layered sulfosalts as electrocatalysts for energy related applications.",
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Layered franckeite and teallite intrinsic heterostructures : Shear exfoliation and electrocatalysis. / Gusmão, Rui; Sofer, Zdeněk; Luxa, Jan; Pumera, Martin.

In: Journal of Materials Chemistry A, Vol. 6, No. 34, 01.01.2018, p. 16590-16599.

Research output: Contribution to journalArticle

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AU - Luxa, Jan

AU - Pumera, Martin

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