Layered Transition-Metal Ditellurides in Electrocatalytic Applications - Contrasting Properties

Jan Luxa, Pavel Vosecký, Vlastimil Mazánek, David Sedmidubský, Martin Pumera, Petr Lazar, Zdenek Sofer

Research output: Contribution to journalArticlepeer-review

30 Citations (Scopus)

Abstract

The layered compounds and especially transition-metal dichalcogenides are at the forefront of current research on electrocatalytic materials. Despite the fact that electrocatalytical properties of molybdenum and tungsten disulfides are well-known, their tellurium analogues are significantly less explored. Here we show an effective method for MoTe2 and WTe2 chemical exfoliation based on alkali metal intercalation and subsequent reaction with water. The as-synthesized and exfoliated tellurides were characterized in detail and investigated for potential application in electrocatalysis. The inherent electrochemical activity related to both cation and anion was observed. This is dominantly related to the oxidation tendency of tellurium. The MoTe2 and WTe2 show significantly contrasting properties toward the hydrogen evolution reaction, where MoTe2 shows highly increased HER activity with little dependence on electrochemical treatment, whereas WTe2 shows slightly worse improvement and strong dependence on the electrochemical treatment. In particular, the exfoliated MoTe2 exhibits improved electrocatalytic activity for hydrogen evolution reaction and possesses a huge application potential.

Original languageEnglish
Pages (from-to)5706-5716
Number of pages11
JournalACS Catalysis
Volume7
Issue number9
DOIs
Publication statusPublished - 2017 Sep 1

Bibliographical note

Funding Information:
Project was supported by Czech Science Foundation (GACR No. 17-11456S and GACR No. 16-05167S) and by specific university research (MSMT No. 20-SVV/2017). This work was created with the financial support of the Neuron Foundation for science support. P.L. acknowledges financial support from the Ministry of Education, Youth and Sports of the Czech Republic via project LO1305. This work was supported by the project Advanced Functional Nanorobots (reg. No. CZ.02.1.01/0.0/0.0/15_003/0000444 financed by the EFRR).

Publisher Copyright:
© 2017 American Chemical Society.

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Fingerprint

Dive into the research topics of 'Layered Transition-Metal Ditellurides in Electrocatalytic Applications - Contrasting Properties'. Together they form a unique fingerprint.

Cite this