Ligand-field symmetry effects in Fe(II) polypyridyl compounds probed by transient X-ray absorption spectroscopy

Hana Cho, Matthew L. Strader, Kiryong Hong, Lindsey Jamula, Eric M. Gullikson, Tae Kyu Kim, Frank M.F. De Groot, James K. McCusker, Robert W. Schoenlein, Nils Huse

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

Ultrafast excited-state evolution in polypyridyl Fe(ii) complexes is of fundamental interest for understanding the origins of the sub-ps spin-state changes that occur upon photoexcitation of this class of compounds as well as for the potential impact such ultrafast dynamics have on incorporation of these compounds in solar energy conversion schemes or switchable optical storage technologies. We have demonstrated that ground-state and, more importantly, ultrafast time-resolved X-ray absorption methods can offer unique insights into the interplay between electronic and geometric structure that underpins the photo-induced dynamics of this class of compounds. The present contribution examines in greater detail how the symmetry of the ligand field surrounding the metal ion can be probed using these X-ray techniques. In particular, we show that steady-state K-edge spectroscopy of the nearest-neighbour nitrogen atoms reveals the characteristic chemical environment of the respective ligands and suggests an interesting target for future charge-transfer femtosecond and attosecond spectroscopy in the X-ray water window.

Original languageEnglish
Pages (from-to)463-474
Number of pages12
JournalFaraday Discussions
Volume157
DOIs
Publication statusPublished - 2012 Jan 1

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X-Ray Absorption Spectroscopy
X ray absorption spectroscopy
absorption spectroscopy
X-Rays
Spectroscopy
Ligands
X rays
ligands
Photoexcitation
Spectrum Analysis
X ray absorption
symmetry
Energy conversion
Excited states
Solar Energy
Solar energy
Ground state
Metal ions
Charge transfer
solar energy conversion

All Science Journal Classification (ASJC) codes

  • Medicine(all)
  • Physical and Theoretical Chemistry

Cite this

Cho, Hana ; Strader, Matthew L. ; Hong, Kiryong ; Jamula, Lindsey ; Gullikson, Eric M. ; Kim, Tae Kyu ; De Groot, Frank M.F. ; McCusker, James K. ; Schoenlein, Robert W. ; Huse, Nils. / Ligand-field symmetry effects in Fe(II) polypyridyl compounds probed by transient X-ray absorption spectroscopy. In: Faraday Discussions. 2012 ; Vol. 157. pp. 463-474.
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Cho, H, Strader, ML, Hong, K, Jamula, L, Gullikson, EM, Kim, TK, De Groot, FMF, McCusker, JK, Schoenlein, RW & Huse, N 2012, 'Ligand-field symmetry effects in Fe(II) polypyridyl compounds probed by transient X-ray absorption spectroscopy', Faraday Discussions, vol. 157, pp. 463-474. https://doi.org/10.1039/c2fd20040f

Ligand-field symmetry effects in Fe(II) polypyridyl compounds probed by transient X-ray absorption spectroscopy. / Cho, Hana; Strader, Matthew L.; Hong, Kiryong; Jamula, Lindsey; Gullikson, Eric M.; Kim, Tae Kyu; De Groot, Frank M.F.; McCusker, James K.; Schoenlein, Robert W.; Huse, Nils.

In: Faraday Discussions, Vol. 157, 01.01.2012, p. 463-474.

Research output: Contribution to journalArticle

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