Light-Driven ZnO Brush-Shaped Self-Propelled Micromachines for Nitroaromatic Explosives Decomposition

Yulong Ying, Amir Masoud Pourrahimi, Carmen Lorena Manzanares-Palenzuela, Filip Novotny, Zdenek Sofer, Martin Pumera

Research output: Contribution to journalArticle

Abstract

Self-propelled micromachines have recently attracted lots of attention for environmental remediation. Developing a large-scale but template-free fabrication of self-propelled rod/tubular micro/nanomotors is very crucial but still challenging. Here, a new strategy based on vertically aligned ZnO arrays is employed for the large-scale and template-free fabrication of self-propelled ZnO-based micromotors with H2O2-free light-driven propulsion ability. Brush-shaped ZnO-based micromotors with different diameters and lengths are fully studied, which present a fast response to multicycles UV light on/off switches with different interval times (2/5 s) in pure water and slow directional motion in aqueous hydrogen peroxide solution in the absence of UV light. Light-induced electrophoretic and self-diffusiophoretic effects are responsible for these two different self-motion behaviors under different conditions, respectively. In addition, the pH of the media and the presence of H2O2 show important effects on the motion behavior and microstructure of the ZnO-based micromotors. Finally, these novel ZnO-based brush-shaped micromotors are demonstrated in a proof-of-concept study on nitroaromatic explosive degradation, i.e., picric acid. This work opens a completely new avenue for the template-free fabrication of brush-shaped light-responsive micromotors on a large scale based on vertically aligned ZnO arrays.

Original languageEnglish
Article number1902944
JournalSmall
DOIs
Publication statusAccepted/In press - 2019 Jan 1

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Micromotors
Brushes
Ultraviolet Rays
Decomposition
Light
Fabrication
Ultraviolet radiation
Hydrogen Peroxide
Water
Hydrogen peroxide
Propulsion
Switches
Degradation
Microstructure
Acids

All Science Journal Classification (ASJC) codes

  • Biotechnology
  • Biomaterials
  • Chemistry(all)
  • Materials Science(all)

Cite this

Ying, Y., Pourrahimi, A. M., Manzanares-Palenzuela, C. L., Novotny, F., Sofer, Z., & Pumera, M. (Accepted/In press). Light-Driven ZnO Brush-Shaped Self-Propelled Micromachines for Nitroaromatic Explosives Decomposition. Small, [1902944]. https://doi.org/10.1002/smll.201902944
Ying, Yulong ; Pourrahimi, Amir Masoud ; Manzanares-Palenzuela, Carmen Lorena ; Novotny, Filip ; Sofer, Zdenek ; Pumera, Martin. / Light-Driven ZnO Brush-Shaped Self-Propelled Micromachines for Nitroaromatic Explosives Decomposition. In: Small. 2019.
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Light-Driven ZnO Brush-Shaped Self-Propelled Micromachines for Nitroaromatic Explosives Decomposition. / Ying, Yulong; Pourrahimi, Amir Masoud; Manzanares-Palenzuela, Carmen Lorena; Novotny, Filip; Sofer, Zdenek; Pumera, Martin.

In: Small, 01.01.2019.

Research output: Contribution to journalArticle

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