Liquid crystal phases generated by supramolecular self-assembly of biforked amphiphilic imidazoles

Oleg N. Kadkin, Jigeon Tae, So Yeon Kim, Eun Ho Kim, Eunji Lee, Moon Gun Choi

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Functional groups with the capability of hydrogen bonding are widely used in the molecular design and preparation of liquid crystalline supramolecular systems, a rapidly growing area of materials showing a high sensitivity towards external stimuli. A series of novel imidazole-containing Schiff's bases replenishing the family of supramolecular liquid crystals has been synthesised and characterised by proton nuclear magnetic resonance, Fourier transform infrared, and ultraviolet-visible spectroscopy, and elemental analyses. Variation of lengths of the terminal alkyl substituents in the obtained amphiphilic imidazoles within 6, 8, 10, 12, 14 and 16 carbon atoms leads to significant changes in their thermal behaviour, micro-segregation and supramolecular self-assembly. Lower homologues were non-mesomorphic, while intermediate members of the homologous series exhibited monotropic bilayered smectic and columnar mesophases. A higher homologue with 16 carbon atoms has an increased trend towards crystallisation of the aliphatic chains and did not exhibit mesomorphism again. The liquid crystalline mesophases were identified and investigated by polarised optical microscopy, differential scanning calorimetry, X-ray diffraction and thermal emission microscopy methods. According to X-ray diffraction characteristics, the smectic mesophase has a bilayered structure where the hydrophilic imidazole groups form a continuous hydrogen bonded network. The interface curvature created by the second alkyl chain leads to the appearance of columnar nanostructures in homologues with 12 and 14 aliphatic carbon atoms.

Original languageEnglish
Pages (from-to)1337-1347
Number of pages11
JournalLiquid Crystals
Volume36
Issue number12
DOIs
Publication statusPublished - 2009 Dec

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Fingerprint Dive into the research topics of 'Liquid crystal phases generated by supramolecular self-assembly of biforked amphiphilic imidazoles'. Together they form a unique fingerprint.

  • Cite this