For the first time, an inorganic-organic hybrid polymer binder was used for the coating of hybrid composites on separators to enhance thermal stability and to prevent formation of lithium dendrite in lithium metal batteries. The fabricated hybrid-composite-coated separators exhibited minimal thermal shrinkage compared with the previous composite separators (<5% change in dimension), maintenance of porosity (Gurley number ∼400 s/100 cm3), and high ionic conductivity (0.82 mS/cm). Lithium metal battery cell examinations with our hybrid-composite-coated separators revealed excellent C-rate and cyclability performance due to the prevention of lithium dendrite growth on the lithium anode even after 200 cycles under 0.2-5C (charge-discharge) conditions. The mechanism for lithium dendrite prevention was attributed to exceptional nanoscale surface mechanical properties of the hybrid composite coating layer compared with the lithium metal anode, as the elastic modulus of the hybrid-composite-coated separator far exceeded those of both the lithium metal anode and the required threshold for lithium metal dendrite prevention.
Bibliographical noteFunding Information:
This work was supported by Fundamental R&D Program for Core Technology of Materials and the Industrial Strategic Technology Development Program funded by the Ministry of Trade, Industry and Energy, Republic of Korea. Partial funding was given by the Materials Architecturing Research Center of Korea Institute of Science and Technology and the Korea Research Fellowship Program funded by the Ministry of Science, ICT, and Future Planning through the National Research Foundation of Korea.
© 2016 American Chemical Society.
All Science Journal Classification (ASJC) codes
- Materials Science(all)