Low-dimensional formamidinium lead perovskite architectures via controllable solvent intercalation

Mingue Shin, Joonyun Kim, Young Kwang Jung, Tero petri Ruoko, Arri Priimagi, Aron Walsh, Byungha Shin

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

We report the formation of a new class of solvent-intercalated two-dimensional (SI-2D) formamidinium lead halide perovskites. They can be mixed with three-dimensional (3D) stoichiometric perovskites by controlling the ratio of the precursor solutions. The composite leads to greatly improved photoluminescence quantum yield (PLQY) over the 3D compound. The enhanced PLQY is attributed to a type-I band alignment between the 3D and SI-2D, as revealed by first-principles calculations, which results in confined excitons with enhanced radiative recombination. The films exhibited excellent thermal and air stability retaining PLQY > 20% over 2 months in ambient conditions. Assemblies of halide perovskites with mixed dimensionality offer a pathway to enhance optoelectronic performance and device lifetimes.

Original languageEnglish
Pages (from-to)3945-3951
Number of pages7
JournalJournal of Materials Chemistry C
Volume7
Issue number13
DOIs
Publication statusPublished - 2019

Bibliographical note

Funding Information:
The work at KAIST was supported by Nano Material Technology Development Program (Green Nano Technology Development Program) through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (No. 2018M3A7B4065662) and National Research Foundation of Korea (NRF) grant funded by the Korea government (No. NRF-2018R1A5A1025594). The work at Yonsei was supported by the Creative Materials Discovery Program through the National Research Foundation of Korea (NRF) funded by Ministry of Science and ICT (2018M3D1A1058536). The work at ICL was supported by the Royal Society and the Leverhulme Trust. Via our membership of the UK’s HEC Materials Chemistry Consortium, which is funded by EPSRC (EP/L000202), this work used the ARCHER supercomputing service. The work at TUT was funded by the Academy of Finland (Grant Number 311142), and by the TUT-KAIST seed funding provided by TUT.

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Low-dimensional formamidinium lead perovskite architectures via controllable solvent intercalation'. Together they form a unique fingerprint.

Cite this