Low-temperature Cu(I) loading on a mesoporous Metal–Organic framework for adsorptive separation of C3H6/C3H8 mixtures

Jung Woon Yoon, Ah Reum Kim, Min June Kim, Tae Ung Yoon, Jeong Hoon Kim, Youn-Sang Bae

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

We incorporated Cu(I) ions into a mesoporous metal–organic framework (MOF) through facile method involving CuCl2 loading, followed by reduction using Na2SO3 as reducing agent. The successful incorporation of Cu(I) ions was supported by various methods such as TEM-EDS, XPS and ICP-AES. Remarkably, the Cu(I) incorporation resulted in 4.2 times higher C3H6/C3H8 selectivity compared with the parent MOF as well as large C3H6 working capacity (1.3 mmol/g) at 10–100 kPa. Moreover, the Cu(I)-loaded MOF showed efficient separation of C3H6 from C3H8 under dynamic mixture flow conditions, easy regeneration under mild conditions, and good stability under atmospheric conditions.

Original languageEnglish
Pages (from-to)271-277
Number of pages7
JournalMicroporous and Mesoporous Materials
Volume279
DOIs
Publication statusPublished - 2019 May 1

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Ions
Reducing Agents
Reducing agents
meteorology
regeneration
Energy dispersive spectroscopy
ions
X ray photoelectron spectroscopy
selectivity
Transmission electron microscopy
Temperature
transmission electron microscopy
cupric chloride

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials

Cite this

Yoon, Jung Woon ; Kim, Ah Reum ; Kim, Min June ; Yoon, Tae Ung ; Kim, Jeong Hoon ; Bae, Youn-Sang. / Low-temperature Cu(I) loading on a mesoporous Metal–Organic framework for adsorptive separation of C3H6/C3H8 mixtures. In: Microporous and Mesoporous Materials. 2019 ; Vol. 279. pp. 271-277.
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Low-temperature Cu(I) loading on a mesoporous Metal–Organic framework for adsorptive separation of C3H6/C3H8 mixtures. / Yoon, Jung Woon; Kim, Ah Reum; Kim, Min June; Yoon, Tae Ung; Kim, Jeong Hoon; Bae, Youn-Sang.

In: Microporous and Mesoporous Materials, Vol. 279, 01.05.2019, p. 271-277.

Research output: Contribution to journalArticle

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T1 - Low-temperature Cu(I) loading on a mesoporous Metal–Organic framework for adsorptive separation of C3H6/C3H8 mixtures

AU - Yoon, Jung Woon

AU - Kim, Ah Reum

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AU - Bae, Youn-Sang

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AB - We incorporated Cu(I) ions into a mesoporous metal–organic framework (MOF) through facile method involving CuCl2 loading, followed by reduction using Na2SO3 as reducing agent. The successful incorporation of Cu(I) ions was supported by various methods such as TEM-EDS, XPS and ICP-AES. Remarkably, the Cu(I) incorporation resulted in 4.2 times higher C3H6/C3H8 selectivity compared with the parent MOF as well as large C3H6 working capacity (1.3 mmol/g) at 10–100 kPa. Moreover, the Cu(I)-loaded MOF showed efficient separation of C3H6 from C3H8 under dynamic mixture flow conditions, easy regeneration under mild conditions, and good stability under atmospheric conditions.

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