Low-Temperature Facile Synthesis of Sb-Doped p-Type ZnO Nanodisks and Its Application in Homojunction Light-Emitting Diode

Sung Doo Baek, Pranab Biswas, Jong Woo Kim, Yun Cheol Kim, Tae Il Lee, Jae Min Myoung

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

This study explores low-temperature solution-process-based seed-layer-free ZnO p-n homojunction light-emitting diode (LED). In order to obtain p-type ZnO nanodisks (NDs), antimony (Sb) was doped into ZnO by using a facile chemical route at 120 °C. The X-ray photoelectron spectra indicated the presence of (SbZn-2VZn) acceptor complex in the Sb-doped ZnO NDs. Using these NDs as freestanding templates, undoped n-type ZnO nanorods (NRs) were epitaxially grown at 95 °C to form ZnO p-n homojunction. The homojunction with a turn-on voltage of 2.5 V was found to be significantly stable up to 100 s under a constant voltage stress of 5 V. A strong orange-red emission was observed by the naked eye under a forward bias of 5 V. The electroluminescence spectra revealed three major peaks at 400, 612, and 742 nm which were attributed to the transitions from Zni to VBM, from Zni to Oi, and from VO to VBM, respectively. The presence of these deep-level defects was confirmed by the photoluminescence of ZnO NRs. This study paves the way for future applications of ZnO homojunction LEDs using low-temperature and low-cost solution processes with the controlled use of native defects.

Original languageEnglish
Pages (from-to)13018-13026
Number of pages9
JournalACS Applied Materials and Interfaces
Volume8
Issue number20
DOIs
Publication statusPublished - 2016 May 25

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Nanorods
Light emitting diodes
Antimony
Defects
Electroluminescence
Electric potential
Photoelectrons
Seed
Photoluminescence
X rays
Temperature
Costs

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

Baek, Sung Doo ; Biswas, Pranab ; Kim, Jong Woo ; Kim, Yun Cheol ; Lee, Tae Il ; Myoung, Jae Min. / Low-Temperature Facile Synthesis of Sb-Doped p-Type ZnO Nanodisks and Its Application in Homojunction Light-Emitting Diode. In: ACS Applied Materials and Interfaces. 2016 ; Vol. 8, No. 20. pp. 13018-13026.
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abstract = "This study explores low-temperature solution-process-based seed-layer-free ZnO p-n homojunction light-emitting diode (LED). In order to obtain p-type ZnO nanodisks (NDs), antimony (Sb) was doped into ZnO by using a facile chemical route at 120 °C. The X-ray photoelectron spectra indicated the presence of (SbZn-2VZn) acceptor complex in the Sb-doped ZnO NDs. Using these NDs as freestanding templates, undoped n-type ZnO nanorods (NRs) were epitaxially grown at 95 °C to form ZnO p-n homojunction. The homojunction with a turn-on voltage of 2.5 V was found to be significantly stable up to 100 s under a constant voltage stress of 5 V. A strong orange-red emission was observed by the naked eye under a forward bias of 5 V. The electroluminescence spectra revealed three major peaks at 400, 612, and 742 nm which were attributed to the transitions from Zni to VBM, from Zni to Oi, and from VO to VBM, respectively. The presence of these deep-level defects was confirmed by the photoluminescence of ZnO NRs. This study paves the way for future applications of ZnO homojunction LEDs using low-temperature and low-cost solution processes with the controlled use of native defects.",
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Low-Temperature Facile Synthesis of Sb-Doped p-Type ZnO Nanodisks and Its Application in Homojunction Light-Emitting Diode. / Baek, Sung Doo; Biswas, Pranab; Kim, Jong Woo; Kim, Yun Cheol; Lee, Tae Il; Myoung, Jae Min.

In: ACS Applied Materials and Interfaces, Vol. 8, No. 20, 25.05.2016, p. 13018-13026.

Research output: Contribution to journalArticle

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