Low temperature steam reforming of methane using metal oxide promoted Ni-Ce0.8Zr0.2O2 catalysts in a compact reformer

Hak Min Kim; Won Jun Jang; Seong Yeun Yoo; Jae Oh Shim; Kyung Won Jeon; Hyun Suk Na; Yeol Lim Lee; Byong Hun Jeon; Jong Wook Bae; Hyun Seog Roh

doi:10.1016/j.ijhydene.2017.11.058

Low temperature steam reforming of methane using metal oxide promoted Ni-Ce_0.8Zr_0.2O₂ catalysts in a compact reformer

Hak Min Kim, Won Jun Jang, Seong Yeun Yoo, Jae Oh Shim, Kyung Won Jeon, Hyun Suk Na, Yeol Lim Lee, Byong Hun Jeon, Jong Wook Bae, Hyun Seog Roh

Division of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Metal oxide (MgO, CaO, and La₂O₃) promoted Ni-Ce_0.8Zr_0.2O₂ catalysts have been applied for low-temperature steam reforming of methane (SRM), and the promoter effect was investigated. The addition of the metal oxides improved the basicity which enhances the resistance coke formation and catalytic activity. Among the prepared catalysts, the Ni-La₂O₃-Ce_0.8Zr_0.2O₂ catalyst exhibited high activity and stability at a very high gas hourly space velocity of 621,704 h⁻¹. This was mainly due to high dispersion of Ni, strong basicity of La₂O₃, and strong interaction between Ni and La₂O₃.

Original language	English
Pages (from-to)	262-270
Number of pages	9
Journal	International Journal of Hydrogen Energy
Volume	43
Issue number	1
DOIs	https://doi.org/10.1016/j.ijhydene.2017.11.058
Publication status	Published - 2018 Jan 4

Bibliographical note

Funding Information:
This work was supported by “Next Generation Carbon Upcycling Project” (Project No. 2017M1A2A2044372 ) through the National Research Foundation (NRF) funded by the Ministry of Science and ICT, Republic of Korea.

All Science Journal Classification (ASJC) codes

Renewable Energy, Sustainability and the Environment
Fuel Technology
Condensed Matter Physics
Energy Engineering and Power Technology

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@article{670080c6fb2a47ff8f5a0f4b1d79387b,

title = "Low temperature steam reforming of methane using metal oxide promoted Ni-Ce0.8Zr0.2O2 catalysts in a compact reformer",

abstract = "Metal oxide (MgO, CaO, and La2O3) promoted Ni-Ce0.8Zr0.2O2 catalysts have been applied for low-temperature steam reforming of methane (SRM), and the promoter effect was investigated. The addition of the metal oxides improved the basicity which enhances the resistance coke formation and catalytic activity. Among the prepared catalysts, the Ni-La2O3-Ce0.8Zr0.2O2 catalyst exhibited high activity and stability at a very high gas hourly space velocity of 621,704 h−1. This was mainly due to high dispersion of Ni, strong basicity of La2O3, and strong interaction between Ni and La2O3.",

author = "Kim, {Hak Min} and Jang, {Won Jun} and Yoo, {Seong Yeun} and Shim, {Jae Oh} and Jeon, {Kyung Won} and Na, {Hyun Suk} and Lee, {Yeol Lim} and Jeon, {Byong Hun} and Bae, {Jong Wook} and Roh, {Hyun Seog}",

note = "Funding Information: This work was supported by “Next Generation Carbon Upcycling Project” (Project No. 2017M1A2A2044372 ) through the National Research Foundation (NRF) funded by the Ministry of Science and ICT, Republic of Korea. ",

year = "2018",

month = jan,

day = "4",

doi = "10.1016/j.ijhydene.2017.11.058",

language = "English",

volume = "43",

pages = "262--270",

journal = "International Journal of Hydrogen Energy",

issn = "0360-3199",

publisher = "Elsevier Limited",

number = "1",

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Low temperature steam reforming of methane using metal oxide promoted Ni-Ce_0.8Zr_0.2O₂ catalysts in a compact reformer. / Kim, Hak Min; Jang, Won Jun; Yoo, Seong Yeun; Shim, Jae Oh; Jeon, Kyung Won; Na, Hyun Suk; Lee, Yeol Lim; Jeon, Byong Hun; Bae, Jong Wook; Roh, Hyun Seog.

In: International Journal of Hydrogen Energy, Vol. 43, No. 1, 04.01.2018, p. 262-270.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Low temperature steam reforming of methane using metal oxide promoted Ni-Ce0.8Zr0.2O2 catalysts in a compact reformer

AU - Kim, Hak Min

AU - Jang, Won Jun

AU - Yoo, Seong Yeun

AU - Shim, Jae Oh

AU - Jeon, Kyung Won

AU - Na, Hyun Suk

AU - Lee, Yeol Lim

AU - Jeon, Byong Hun

AU - Bae, Jong Wook

AU - Roh, Hyun Seog

N1 - Funding Information: This work was supported by “Next Generation Carbon Upcycling Project” (Project No. 2017M1A2A2044372 ) through the National Research Foundation (NRF) funded by the Ministry of Science and ICT, Republic of Korea.

PY - 2018/1/4

Y1 - 2018/1/4

N2 - Metal oxide (MgO, CaO, and La2O3) promoted Ni-Ce0.8Zr0.2O2 catalysts have been applied for low-temperature steam reforming of methane (SRM), and the promoter effect was investigated. The addition of the metal oxides improved the basicity which enhances the resistance coke formation and catalytic activity. Among the prepared catalysts, the Ni-La2O3-Ce0.8Zr0.2O2 catalyst exhibited high activity and stability at a very high gas hourly space velocity of 621,704 h−1. This was mainly due to high dispersion of Ni, strong basicity of La2O3, and strong interaction between Ni and La2O3.

AB - Metal oxide (MgO, CaO, and La2O3) promoted Ni-Ce0.8Zr0.2O2 catalysts have been applied for low-temperature steam reforming of methane (SRM), and the promoter effect was investigated. The addition of the metal oxides improved the basicity which enhances the resistance coke formation and catalytic activity. Among the prepared catalysts, the Ni-La2O3-Ce0.8Zr0.2O2 catalyst exhibited high activity and stability at a very high gas hourly space velocity of 621,704 h−1. This was mainly due to high dispersion of Ni, strong basicity of La2O3, and strong interaction between Ni and La2O3.

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