Möbius Aromatic [28]Hexaphyrin Germanium(IV) and Tin(IV) Complexes: Efficient Formation of Triplet Excited States

Mondo Izawa; Taeyeon Kim; Shin Ichiro Ishida; Takayuki Tanaka; Tadashi Mori; Dongho Kim; Atsuhiro Osuka

doi:10.1002/anie.201700063

Möbius Aromatic [28]Hexaphyrin Germanium(IV) and Tin(IV) Complexes: Efficient Formation of Triplet Excited States

Mondo Izawa, Taeyeon Kim, Shin Ichiro Ishida, Takayuki Tanaka, Tadashi Mori, Dongho Kim, Atsuhiro Osuka

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

[28]Hexaphyrin Ge^IV and Sn^IV complexes were synthesized in high yields by reactions of [28]hexaphyrin with GeCl₄ or SnCl₄ in the presence of triethylamine. Both complexes display distinct 28π Möbius aromatic character and possess a trigonal bipyramidal geometry at the central Ge^IV or Sn^IV atom. The equatorial hydroxy group of the Ge^IV complex was smoothly exchanged with neutral nucleophiles, such as phenol derivatives and thiophenol, with retention of configuration. In the Sn^IV complex, intersystem crossing to the T₁ state is remarkably enhanced owing to the effective heavy-atom effect, thus allowing the formation of the T₁ state in high yield. The T₁ states of the Ge^IV and Sn^VI complexes were found to be antiaromatic on the basis of the transient absorption features in line with the Baird rule.

Original language	English
Pages (from-to)	3982-3986
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	56
Issue number	14
DOIs	https://doi.org/10.1002/anie.201700063
Publication status	Published - 2017 Mar 27

Bibliographical note

Funding Information:
The research at Kyoto and Osaka was supported by JSPS KAKENHI grants 25220802, 16K13952, 26810021, JP16H00909, JP15H03779, JP15K13642, and JP15H01087. S.-i.I. acknowledges a JSPS Fellowship for Young Scientists. The research at Yonsei University was supported by Global Research Laboratory grant 2013K1A1A2A02050183. The quantum-mechanical calculations were supported by the National Institute of Supercomputing and Network (NISN)/Korea Institute of Science and Technology Information (KISTI) with supercomputing resources, including technical support (KSC-2015-C3-024).

Publisher Copyright:
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/anie.201700063

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title = "M{\"o}bius Aromatic [28]Hexaphyrin Germanium(IV) and Tin(IV) Complexes: Efficient Formation of Triplet Excited States",

abstract = "[28]Hexaphyrin GeIV and SnIV complexes were synthesized in high yields by reactions of [28]hexaphyrin with GeCl4 or SnCl4 in the presence of triethylamine. Both complexes display distinct 28π M{\"o}bius aromatic character and possess a trigonal bipyramidal geometry at the central GeIV or SnIV atom. The equatorial hydroxy group of the GeIV complex was smoothly exchanged with neutral nucleophiles, such as phenol derivatives and thiophenol, with retention of configuration. In the SnIV complex, intersystem crossing to the T1 state is remarkably enhanced owing to the effective heavy-atom effect, thus allowing the formation of the T1 state in high yield. The T1 states of the GeIV and SnVI complexes were found to be antiaromatic on the basis of the transient absorption features in line with the Baird rule.",

author = "Mondo Izawa and Taeyeon Kim and Ishida, {Shin Ichiro} and Takayuki Tanaka and Tadashi Mori and Dongho Kim and Atsuhiro Osuka",

note = "Funding Information: The research at Kyoto and Osaka was supported by JSPS KAKENHI grants 25220802, 16K13952, 26810021, JP16H00909, JP15H03779, JP15K13642, and JP15H01087. S.-i.I. acknowledges a JSPS Fellowship for Young Scientists. The research at Yonsei University was supported by Global Research Laboratory grant 2013K1A1A2A02050183. The quantum-mechanical calculations were supported by the National Institute of Supercomputing and Network (NISN)/Korea Institute of Science and Technology Information (KISTI) with supercomputing resources, including technical support (KSC-2015-C3-024). Publisher Copyright: {\textcopyright} 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",

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AU - Ishida, Shin Ichiro

AU - Tanaka, Takayuki

AU - Mori, Tadashi

AU - Kim, Dongho

AU - Osuka, Atsuhiro

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PY - 2017/3/27

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N2 - [28]Hexaphyrin GeIV and SnIV complexes were synthesized in high yields by reactions of [28]hexaphyrin with GeCl4 or SnCl4 in the presence of triethylamine. Both complexes display distinct 28π Möbius aromatic character and possess a trigonal bipyramidal geometry at the central GeIV or SnIV atom. The equatorial hydroxy group of the GeIV complex was smoothly exchanged with neutral nucleophiles, such as phenol derivatives and thiophenol, with retention of configuration. In the SnIV complex, intersystem crossing to the T1 state is remarkably enhanced owing to the effective heavy-atom effect, thus allowing the formation of the T1 state in high yield. The T1 states of the GeIV and SnVI complexes were found to be antiaromatic on the basis of the transient absorption features in line with the Baird rule.

AB - [28]Hexaphyrin GeIV and SnIV complexes were synthesized in high yields by reactions of [28]hexaphyrin with GeCl4 or SnCl4 in the presence of triethylamine. Both complexes display distinct 28π Möbius aromatic character and possess a trigonal bipyramidal geometry at the central GeIV or SnIV atom. The equatorial hydroxy group of the GeIV complex was smoothly exchanged with neutral nucleophiles, such as phenol derivatives and thiophenol, with retention of configuration. In the SnIV complex, intersystem crossing to the T1 state is remarkably enhanced owing to the effective heavy-atom effect, thus allowing the formation of the T1 state in high yield. The T1 states of the GeIV and SnVI complexes were found to be antiaromatic on the basis of the transient absorption features in line with the Baird rule.

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Möbius Aromatic [28]Hexaphyrin Germanium(IV) and Tin(IV) Complexes: Efficient Formation of Triplet Excited States

Abstract

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