TY - JOUR
T1 - Möbius antiaromatic bisphosphorus complexes of [30]hexaphyrins
AU - Higashino, Tomohiro
AU - Lim, Jong Min
AU - Miura, Takahiro
AU - Saito, Shohei
AU - Shin, Jae Yoon
AU - Kim, Dongho
AU - Osuka, Atsuhiro
PY - 2010/7/5
Y1 - 2010/7/5
N2 - Aromaticity with a twist: The reversal of Möbius aromaticity occurs by changing the number of π electrons between [4n + 2] and [4n] in monophosphorus complexes of [28]hexaphyrins and bisphosphorus complexes of [30]hexaphyrins. The 30π Möbius antiaromatic bisphosporus[30]hexaphyrins (see picture) were determined to be the first structurally characterized Möbius antiaromatic systems, which are rigid, neutral, and stable. (Figure Presented)
AB - Aromaticity with a twist: The reversal of Möbius aromaticity occurs by changing the number of π electrons between [4n + 2] and [4n] in monophosphorus complexes of [28]hexaphyrins and bisphosphorus complexes of [30]hexaphyrins. The 30π Möbius antiaromatic bisphosporus[30]hexaphyrins (see picture) were determined to be the first structurally characterized Möbius antiaromatic systems, which are rigid, neutral, and stable. (Figure Presented)
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U2 - 10.1002/anie.201001765
DO - 10.1002/anie.201001765
M3 - Article
C2 - 20521298
AN - SCOPUS:77954330861
SN - 1433-7851
VL - 49
SP - 4950
EP - 4954
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 29
ER -