Möbius antiaromatic bisphosphorus complexes of [30]hexaphyrins

Tomohiro Higashino, Jong Min Lim, Takahiro Miura, Shohei Saito, Jae Yoon Shin, Dongho Kim, Atsuhiro Osuka

Research output: Contribution to journalArticle

86 Citations (Scopus)

Abstract

Aromaticity with a twist: The reversal of Möbius aromaticity occurs by changing the number of π electrons between [4n + 2] and [4n] in monophosphorus complexes of [28]hexaphyrins and bisphosphorus complexes of [30]hexaphyrins. The 30π Möbius antiaromatic bisphosporus[30]hexaphyrins (see picture) were determined to be the first structurally characterized Möbius antiaromatic systems, which are rigid, neutral, and stable. (Figure Presented)

Original languageEnglish
Pages (from-to)4950-4954
Number of pages5
JournalAngewandte Chemie - International Edition
Volume49
Issue number29
DOIs
Publication statusPublished - 2010 Jul 5

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Electrons

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Higashino, T., Lim, J. M., Miura, T., Saito, S., Shin, J. Y., Kim, D., & Osuka, A. (2010). Möbius antiaromatic bisphosphorus complexes of [30]hexaphyrins. Angewandte Chemie - International Edition, 49(29), 4950-4954. https://doi.org/10.1002/anie.201001765
Higashino, Tomohiro ; Lim, Jong Min ; Miura, Takahiro ; Saito, Shohei ; Shin, Jae Yoon ; Kim, Dongho ; Osuka, Atsuhiro. / Möbius antiaromatic bisphosphorus complexes of [30]hexaphyrins. In: Angewandte Chemie - International Edition. 2010 ; Vol. 49, No. 29. pp. 4950-4954.
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Higashino, T, Lim, JM, Miura, T, Saito, S, Shin, JY, Kim, D & Osuka, A 2010, 'Möbius antiaromatic bisphosphorus complexes of [30]hexaphyrins', Angewandte Chemie - International Edition, vol. 49, no. 29, pp. 4950-4954. https://doi.org/10.1002/anie.201001765

Möbius antiaromatic bisphosphorus complexes of [30]hexaphyrins. / Higashino, Tomohiro; Lim, Jong Min; Miura, Takahiro; Saito, Shohei; Shin, Jae Yoon; Kim, Dongho; Osuka, Atsuhiro.

In: Angewandte Chemie - International Edition, Vol. 49, No. 29, 05.07.2010, p. 4950-4954.

Research output: Contribution to journalArticle

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AU - Lim, Jong Min

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AU - Kim, Dongho

AU - Osuka, Atsuhiro

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