Magnetic nanoparticle-embedded PCM nanocapsules based on paraffin core and polyurea shell

Sangphil Park, Yeongmin Lee, Yong Seok Kim, Hyang Moo Lee, Jung-Hyun Kim, In Woo Cheong, Won-Gun Koh

Research output: Contribution to journalArticle

49 Citations (Scopus)

Abstract

We described the synthesis and characterization of magnetic Fe3O4 nanoparticle (NP)-embedded phase change material (PCM) nanocapsules (Mag-PCM) based on a paraffin core and polyurea shell (paraffin@polyurea). The Mag-PCM nanocapsules were synthesized via interfacial polycondensation between tolylene diisocyanate (TDI) and ethylene diamine (EDA) with various concentrations (0, 2.2, 3.7, and 4.6wt%) of Fe3O4 nanoparticles. FTIR and TGA analyses confirmed the successful preparation of Mag-PCM nanocapsules. TEM and SEM images revealed that most of the Fe3O4 NPs were localized in the polyurea shell layer due to the Pickering effect. Laser flash (LFA) and DSC analyses demonstrated that the embedment of Fe3O4 NPs could increase the thermal conductivity of PCM nanocapsules and reduce the supercooling of the paraffin between bulk and nano-size confinement conditions.

Original languageEnglish
Pages (from-to)46-51
Number of pages6
JournalColloids and Surfaces A: Physicochemical and Engineering Aspects
Volume450
Issue number1
DOIs
Publication statusPublished - 2014 May 20

Fingerprint

Nanocapsules
phase change materials
Phase change materials
paraffins
Paraffin
Paraffins
Nanoparticles
nanoparticles
Interfacial polycondensation
Toluene 2,4-Diisocyanate
diisocyanates
Supercooling
Diamines
supercooling
ethylenediamine
flash
Thermal conductivity
Ethylene
thermal conductivity
polyurea

All Science Journal Classification (ASJC) codes

  • Surfaces and Interfaces
  • Physical and Theoretical Chemistry
  • Colloid and Surface Chemistry

Cite this

Park, Sangphil ; Lee, Yeongmin ; Kim, Yong Seok ; Lee, Hyang Moo ; Kim, Jung-Hyun ; Cheong, In Woo ; Koh, Won-Gun. / Magnetic nanoparticle-embedded PCM nanocapsules based on paraffin core and polyurea shell. In: Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2014 ; Vol. 450, No. 1. pp. 46-51.
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Magnetic nanoparticle-embedded PCM nanocapsules based on paraffin core and polyurea shell. / Park, Sangphil; Lee, Yeongmin; Kim, Yong Seok; Lee, Hyang Moo; Kim, Jung-Hyun; Cheong, In Woo; Koh, Won-Gun.

In: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 450, No. 1, 20.05.2014, p. 46-51.

Research output: Contribution to journalArticle

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