Matrix-assisted synthesis of palladium nanocage and nanowires

J. Cheon, K. B. Lee, H. Kang, S. J. Oh, H. C. Ri

Research output: Contribution to journalConference article

4 Citations (Scopus)

Abstract

Our study describes the synthesis of novel nanoscale Pd cage and wires whose sizes and shapes are templated by mesoporous matrices. The templates used are cubic phase MCM-48 and hexagonal phase CnMCM-41 (n = 16, and 22), SBA-15, which have pore diameters of ∼3, ∼3.8, ∼4.7, and ∼9 nm, respectively. For Pd@MCM-48, the Pd metal forms spherical domains (∼ 38 nm) consisting of three dimensionally interconnected into Pd arrays; for Pd@SBA-15 and Pd@MCM-41, the Pd metal forms of one-dimensional wires. Etching out the matrix produces porous Pd cages (pore sizes of ∼1.5 - 2.0 nm) with retaining original domain sizes of ∼38 nm; similarly Pd@SBA-15 and Pd@MCM-41 afford freestanding Pd nanowires. All the materials are examined by TEM, XRD, BET, and EDAX analysis. Furthermore, the thermal behaviour of Pd nanowire is briefly described.

Original languageEnglish
Pages (from-to)C331-C336
JournalMaterials Research Society Symposium - Proceedings
Volume635
Publication statusPublished - 2001 Jan 1
EventAnisotropic Nanoparticles-Synthesis, Characterization and Applications - Boston, MA, United States
Duration: 2000 Nov 272000 Nov 29

Fingerprint

Palladium
Multicarrier modulation
Nanowires
palladium
nanowires
synthesis
matrices
Metals
wire
Wire
porosity
retaining
metals
Pore size
Energy dispersive spectroscopy
Etching
templates
etching
Transmission electron microscopy
transmission electron microscopy

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Cheon, J. ; Lee, K. B. ; Kang, H. ; Oh, S. J. ; Ri, H. C. / Matrix-assisted synthesis of palladium nanocage and nanowires. In: Materials Research Society Symposium - Proceedings. 2001 ; Vol. 635. pp. C331-C336.
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Matrix-assisted synthesis of palladium nanocage and nanowires. / Cheon, J.; Lee, K. B.; Kang, H.; Oh, S. J.; Ri, H. C.

In: Materials Research Society Symposium - Proceedings, Vol. 635, 01.01.2001, p. C331-C336.

Research output: Contribution to journalConference article

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T1 - Matrix-assisted synthesis of palladium nanocage and nanowires

AU - Cheon, J.

AU - Lee, K. B.

AU - Kang, H.

AU - Oh, S. J.

AU - Ri, H. C.

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N2 - Our study describes the synthesis of novel nanoscale Pd cage and wires whose sizes and shapes are templated by mesoporous matrices. The templates used are cubic phase MCM-48 and hexagonal phase CnMCM-41 (n = 16, and 22), SBA-15, which have pore diameters of ∼3, ∼3.8, ∼4.7, and ∼9 nm, respectively. For Pd@MCM-48, the Pd metal forms spherical domains (∼ 38 nm) consisting of three dimensionally interconnected into Pd arrays; for Pd@SBA-15 and Pd@MCM-41, the Pd metal forms of one-dimensional wires. Etching out the matrix produces porous Pd cages (pore sizes of ∼1.5 - 2.0 nm) with retaining original domain sizes of ∼38 nm; similarly Pd@SBA-15 and Pd@MCM-41 afford freestanding Pd nanowires. All the materials are examined by TEM, XRD, BET, and EDAX analysis. Furthermore, the thermal behaviour of Pd nanowire is briefly described.

AB - Our study describes the synthesis of novel nanoscale Pd cage and wires whose sizes and shapes are templated by mesoporous matrices. The templates used are cubic phase MCM-48 and hexagonal phase CnMCM-41 (n = 16, and 22), SBA-15, which have pore diameters of ∼3, ∼3.8, ∼4.7, and ∼9 nm, respectively. For Pd@MCM-48, the Pd metal forms spherical domains (∼ 38 nm) consisting of three dimensionally interconnected into Pd arrays; for Pd@SBA-15 and Pd@MCM-41, the Pd metal forms of one-dimensional wires. Etching out the matrix produces porous Pd cages (pore sizes of ∼1.5 - 2.0 nm) with retaining original domain sizes of ∼38 nm; similarly Pd@SBA-15 and Pd@MCM-41 afford freestanding Pd nanowires. All the materials are examined by TEM, XRD, BET, and EDAX analysis. Furthermore, the thermal behaviour of Pd nanowire is briefly described.

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