The quantitative aminolysis reactions were successfully achieved by reacting PBLA with a variety of primary amines.The specific rotations of the poly(aspartamide) derivatives synthesized by this reaction depend on the initial condition of the hyper structure of PBLA in the solvents. The mechanism of this reaction may occur not just only through the ester-amide exchange on the side chain but also through the transformation involving α -methine and β -methylene, which also effect the specific rotation.
|Number of pages||1|
|Publication status||Published - 2006 Oct 18|
|Event||55th SPSJ Annual Meeting - Nagoya, Japan|
Duration: 2006 May 24 → 2006 May 26
|Other||55th SPSJ Annual Meeting|
|Period||06/5/24 → 06/5/26|
All Science Journal Classification (ASJC) codes