Mechanism of field emission from chemical vapor deposited undoped poly crystalline diamond films

Jae Yeob Shim, Hong Koo Baik, Kie Moon Song

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Field emission characteristics of undoped polycrystalline diamond films with different structural properties have been investigated. By introducing positive bias voltage and/or increasing CH4/H2 ratio, the film quality is significantly deteriorated together with the increase of nondiamond carbon component and the surface morphologies of the films lost their unique facet shape. The reason for the increase of nondiamond carbon content is described in terms of both the increase of substrate temperature and the excessive generation of CHn radicals. It is confirmed that an increase in the nondiamond carbon content markedly enhances field emission properties of diamond films. From the spatial distribution of emission sites, it is suggested that the transport path of field-emitted electrons depends on the nondiamond carbon content: for the film with a large amount of nondiamond carbon, electrons transport preferentially through the conducting mediums such as grain boundaries while for the film with a relatively small amount of nondiamond carbon, electron transport occurs mainly through the diamond surface.

Original languageEnglish
Pages (from-to)7508-7518
Number of pages11
JournalJournal of Applied Physics
Volume87
Issue number10
DOIs
Publication statusPublished - 2000 May 15

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diamond films
field emission
vapors
carbon
electrons
flat surfaces
spatial distribution
grain boundaries
conductors
diamonds
electric potential

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)

Cite this

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abstract = "Field emission characteristics of undoped polycrystalline diamond films with different structural properties have been investigated. By introducing positive bias voltage and/or increasing CH4/H2 ratio, the film quality is significantly deteriorated together with the increase of nondiamond carbon component and the surface morphologies of the films lost their unique facet shape. The reason for the increase of nondiamond carbon content is described in terms of both the increase of substrate temperature and the excessive generation of CHn radicals. It is confirmed that an increase in the nondiamond carbon content markedly enhances field emission properties of diamond films. From the spatial distribution of emission sites, it is suggested that the transport path of field-emitted electrons depends on the nondiamond carbon content: for the film with a large amount of nondiamond carbon, electrons transport preferentially through the conducting mediums such as grain boundaries while for the film with a relatively small amount of nondiamond carbon, electron transport occurs mainly through the diamond surface.",
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Mechanism of field emission from chemical vapor deposited undoped poly crystalline diamond films. / Shim, Jae Yeob; Baik, Hong Koo; Song, Kie Moon.

In: Journal of Applied Physics, Vol. 87, No. 10, 15.05.2000, p. 7508-7518.

Research output: Contribution to journalArticle

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AU - Song, Kie Moon

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AB - Field emission characteristics of undoped polycrystalline diamond films with different structural properties have been investigated. By introducing positive bias voltage and/or increasing CH4/H2 ratio, the film quality is significantly deteriorated together with the increase of nondiamond carbon component and the surface morphologies of the films lost their unique facet shape. The reason for the increase of nondiamond carbon content is described in terms of both the increase of substrate temperature and the excessive generation of CHn radicals. It is confirmed that an increase in the nondiamond carbon content markedly enhances field emission properties of diamond films. From the spatial distribution of emission sites, it is suggested that the transport path of field-emitted electrons depends on the nondiamond carbon content: for the film with a large amount of nondiamond carbon, electrons transport preferentially through the conducting mediums such as grain boundaries while for the film with a relatively small amount of nondiamond carbon, electron transport occurs mainly through the diamond surface.

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