Meso-Arylethynyl subporphyrins as efficient and tunable photo-induced electron transfer units

Won Young Cha, Juwon Oh, Masaaki Kitano, Atsuhiro Osuka, Dongho Kim

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Excited state dynamics of meso-Arylethynyl-substituted subporphyrins can be tuned by 4-substituent at the arylethynyl group and solvent polarity. In polar acetonitrile, phenylethynyl subporphyrin 1 exhibited enhanced fluorescence, while (4-dimethylaminophenyl)ethynyl subporphyrin 2 showed red-shifted fluorescence from its charge-separated state and (4-nitrophenyl)ethynyl subporphyrin 3 displayed efficient fluorescence quenching due to charge separation.

Original languageEnglish
Pages (from-to)152-157
Number of pages6
JournalJournal of Porphyrins and Phthalocyanines
Volume21
Issue number2
DOIs
Publication statusPublished - 2017 Feb 1

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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