Meso-Arylethynyl subporphyrins as efficient and tunable photo-induced electron transfer units

Won Young Cha, Juwon Oh, Masaaki Kitano, Atsuhiro Osuka, Dongho Kim

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Excited state dynamics of meso-Arylethynyl-substituted subporphyrins can be tuned by 4-substituent at the arylethynyl group and solvent polarity. In polar acetonitrile, phenylethynyl subporphyrin 1 exhibited enhanced fluorescence, while (4-dimethylaminophenyl)ethynyl subporphyrin 2 showed red-shifted fluorescence from its charge-separated state and (4-nitrophenyl)ethynyl subporphyrin 3 displayed efficient fluorescence quenching due to charge separation.

Original languageEnglish
Pages (from-to)152-157
Number of pages6
JournalJournal of Porphyrins and Phthalocyanines
Volume21
Issue number2
DOIs
Publication statusPublished - 2017 Feb 1

Bibliographical note

Funding Information:
The work at Yonsei University was financially supported by Global Research Laboratory (2013K1A1A2A02050183) through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT (Information and Communication Technologies) and Future Planning. The quantum calculations were performed using the supercomputing resources of the Korea Institute of Science and Technology Information (KISTI).

Publisher Copyright:
© 2017 World Scientific Publishing Company.

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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