Metal-catalysed alkyl ketone to ethyl ketone conversions in chelating ketones via carbon-carbon bond cleavage

J. William Suggs, Chul Ho Jun

Research output: Contribution to journalArticle

92 Citations (Scopus)

Abstract

8-Quinolinyl alkyl ketones, in which the alkyl group has β-hydrogens, react with various Rh| and lr| complexes under ethylene to give, in a catalytic process, 8-quinolinyl ethyl ketone; the same reaction with 8-quinolinyl phenyl ketone produces styrene via ethylene insertion into a rhodium-phenyl bond and β-elimination of the resulting phenylethyl complex.

Original languageEnglish
Pages (from-to)92-93
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number2
DOIs
Publication statusPublished - 1985 Jan 1

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Chelation
Ketones
Carbon
Metals
Ethylene
Rhodium
Styrene
Hydrogen
ethylene

All Science Journal Classification (ASJC) codes

  • Molecular Medicine

Cite this

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abstract = "8-Quinolinyl alkyl ketones, in which the alkyl group has β-hydrogens, react with various Rh| and lr| complexes under ethylene to give, in a catalytic process, 8-quinolinyl ethyl ketone; the same reaction with 8-quinolinyl phenyl ketone produces styrene via ethylene insertion into a rhodium-phenyl bond and β-elimination of the resulting phenylethyl complex.",
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