"Metal-free" catalytic oxygen reduction reaction on heteroatom-doped graphene is caused by trace metal impurities

Lu Wang, Adriano Ambrosi, Martin Pumera

Research output: Contribution to journalArticle

254 Citations (Scopus)

Abstract

The oxygen reduction reaction (ORR) is of high industrial importance. There is a large body of literature showing that metal-based catalytic nanoparticles (e.g. Co, Mn, Fe or hybrid Mn/Co-based nanoparticles) supported on graphene act as efficient catalysts for the ORR. A significant research effort is also directed to the so-called "metal-free" oxygen reduction reaction on heteroatom-doped graphene surfaces. While such studies of the ORR on nonmetallic heteroatom-doped graphene are advertised as "metal-free" there is typically no sufficient effort to characterize the doped materials to verify that they are indeed free of any trace metal. Here we argue that the claimed "metal-free" electrocatalysis of the oxygen reduction reaction on heteroatom-doped graphene is caused by metallic impurities present within the graphene materials. Carbon materials: Heteroatom-doped graphene surfaces are used as electrocatalysts for the oxygen reduction reaction. The claimed "metal-free" electrocatalysis of the oxygen reduction reaction is caused by metallic impurities (see picture) present within the graphene materials.

Original languageEnglish
Pages (from-to)13818-13821
Number of pages4
JournalAngewandte Chemie - International Edition
Volume52
Issue number51
DOIs
Publication statusPublished - 2013 Dec 16

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Graphene
Metals
Impurities
Oxygen
Electrocatalysis
Nanoparticles
Electrocatalysts
Trace metals
Carbon
Catalysts

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

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abstract = "The oxygen reduction reaction (ORR) is of high industrial importance. There is a large body of literature showing that metal-based catalytic nanoparticles (e.g. Co, Mn, Fe or hybrid Mn/Co-based nanoparticles) supported on graphene act as efficient catalysts for the ORR. A significant research effort is also directed to the so-called {"}metal-free{"} oxygen reduction reaction on heteroatom-doped graphene surfaces. While such studies of the ORR on nonmetallic heteroatom-doped graphene are advertised as {"}metal-free{"} there is typically no sufficient effort to characterize the doped materials to verify that they are indeed free of any trace metal. Here we argue that the claimed {"}metal-free{"} electrocatalysis of the oxygen reduction reaction on heteroatom-doped graphene is caused by metallic impurities present within the graphene materials. Carbon materials: Heteroatom-doped graphene surfaces are used as electrocatalysts for the oxygen reduction reaction. The claimed {"}metal-free{"} electrocatalysis of the oxygen reduction reaction is caused by metallic impurities (see picture) present within the graphene materials.",
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"Metal-free" catalytic oxygen reduction reaction on heteroatom-doped graphene is caused by trace metal impurities. / Wang, Lu; Ambrosi, Adriano; Pumera, Martin.

In: Angewandte Chemie - International Edition, Vol. 52, No. 51, 16.12.2013, p. 13818-13821.

Research output: Contribution to journalArticle

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