Abstract
This paper investigated the catalytic activity of cobalt and its alloy with molybdenum for the growth of single-walled carbon nanotubes (SWCNT) using the CVD process. The phase transformation of the Co-Mo catalyst was monitored during high temperature methane pyrolysis to determine the catalytic activity of each element for graphitization, and the results can be applied to synthesize SWCNT with high efficiency. Structural changes through the formation of the intermetallic compound Co3Mo and decomposition during the CVD reaction generated the internal instability of the metal catalyst, and this played a crucial role in the nucleation of a graphitic structure and the promotion of SWCNT growth.
| Original language | English |
|---|---|
| Pages (from-to) | 219-222 |
| Number of pages | 4 |
| Journal | Journal of Alloys and Compounds |
| Volume | 493 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - 2010 Mar 18 |
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All Science Journal Classification (ASJC) codes
- Mechanical Engineering
- Mechanics of Materials
- Materials Chemistry
- Metals and Alloys
Cite this
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Metal-induced graphitization by methane pyrolysis : Its application as a catalyst for single-walled carbon nanotubes. / Yoon, Young Joon; Baik, Hong Koo.
In: Journal of Alloys and Compounds, Vol. 493, No. 1-2, 18.03.2010, p. 219-222.Research output: Contribution to journal › Article
TY - JOUR
T1 - Metal-induced graphitization by methane pyrolysis
T2 - Its application as a catalyst for single-walled carbon nanotubes
AU - Yoon, Young Joon
AU - Baik, Hong Koo
PY - 2010/3/18
Y1 - 2010/3/18
N2 - This paper investigated the catalytic activity of cobalt and its alloy with molybdenum for the growth of single-walled carbon nanotubes (SWCNT) using the CVD process. The phase transformation of the Co-Mo catalyst was monitored during high temperature methane pyrolysis to determine the catalytic activity of each element for graphitization, and the results can be applied to synthesize SWCNT with high efficiency. Structural changes through the formation of the intermetallic compound Co3Mo and decomposition during the CVD reaction generated the internal instability of the metal catalyst, and this played a crucial role in the nucleation of a graphitic structure and the promotion of SWCNT growth.
AB - This paper investigated the catalytic activity of cobalt and its alloy with molybdenum for the growth of single-walled carbon nanotubes (SWCNT) using the CVD process. The phase transformation of the Co-Mo catalyst was monitored during high temperature methane pyrolysis to determine the catalytic activity of each element for graphitization, and the results can be applied to synthesize SWCNT with high efficiency. Structural changes through the formation of the intermetallic compound Co3Mo and decomposition during the CVD reaction generated the internal instability of the metal catalyst, and this played a crucial role in the nucleation of a graphitic structure and the promotion of SWCNT growth.
UR - http://www.scopus.com/inward/record.url?scp=77249134100&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=77249134100&partnerID=8YFLogxK
U2 - 10.1016/j.jallcom.2009.12.058
DO - 10.1016/j.jallcom.2009.12.058
M3 - Article
VL - 493
SP - 219
EP - 222
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
SN - 0925-8388
IS - 1-2
ER -