Metal-mediated self-assembly of π-bonded benzoquinone complexes into polymers with tunable geometries

Moonhyun Oh, Gene B. Carpenter, Dwight A. Sweigart

Research output: Contribution to journalArticle

63 Citations (Scopus)

Abstract

Coordination of Mn(CO)3+ to the π system in hydroquinone facilitates proton loss to afford benzoquinone complexes (see figure). Subsequent σ coordination of the benzoquinone oxygen atoms to added metal ions results in neutral one-, two-, or three-dimensional quinoid polymers. The geometrical requirements of the metal ion and the presence of added "spacer" ligands dictate the type of polymer formed.

Original languageEnglish
Pages (from-to)3191-3194
Number of pages4
JournalAngewandte Chemie - International Edition
Volume40
Issue number17
DOIs
Publication statusPublished - 2001 Sep 3

Fingerprint

Self assembly
Metal ions
Polymers
Metals
Geometry
Carbon Monoxide
Protons
Ligands
Oxygen
Atoms
benzoquinone
hydroquinone

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

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Metal-mediated self-assembly of π-bonded benzoquinone complexes into polymers with tunable geometries. / Oh, Moonhyun; Carpenter, Gene B.; Sweigart, Dwight A.

In: Angewandte Chemie - International Edition, Vol. 40, No. 17, 03.09.2001, p. 3191-3194.

Research output: Contribution to journalArticle

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