Metal-mediated self-assembly of π-bonded benzoquinone complexes into polymers with tunable geometries

Moonhyun Oh; Gene B. Carpenter; Dwight A. Sweigart

doi:10.1002/1521-3773(20010903)40:17<3191::AID-ANIE3191>3.0.CO;2-N

Metal-mediated self-assembly of π-bonded benzoquinone complexes into polymers with tunable geometries

Moonhyun Oh, Gene B. Carpenter, Dwight A. Sweigart

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

64 Citations (Scopus)

Abstract

Coordination of Mn(CO)₃⁺ to the π system in hydroquinone facilitates proton loss to afford benzoquinone complexes (see figure). Subsequent σ coordination of the benzoquinone oxygen atoms to added metal ions results in neutral one-, two-, or three-dimensional quinoid polymers. The geometrical requirements of the metal ion and the presence of added "spacer" ligands dictate the type of polymer formed.

Original language	English
Pages (from-to)	3191-3194
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	17
DOIs	https://doi.org/10.1002/1521-3773(20010903)40:17<3191::AID-ANIE3191>3.0.CO;2-N
Publication status	Published - 2001 Sep 3

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/1521-3773(20010903)40:17<3191::AID-ANIE3191>3.0.CO;2-N

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AB - Coordination of Mn(CO)3+ to the π system in hydroquinone facilitates proton loss to afford benzoquinone complexes (see figure). Subsequent σ coordination of the benzoquinone oxygen atoms to added metal ions results in neutral one-, two-, or three-dimensional quinoid polymers. The geometrical requirements of the metal ion and the presence of added "spacer" ligands dictate the type of polymer formed.

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