TY - JOUR
T1 - Metal-mediated self-assembly of π-bonded benzoquinone complexes into polymers with tunable geometries
AU - Oh, Moonhyun
AU - Carpenter, Gene B.
AU - Sweigart, Dwight A.
PY - 2001/9/3
Y1 - 2001/9/3
N2 - Coordination of Mn(CO)3+ to the π system in hydroquinone facilitates proton loss to afford benzoquinone complexes (see figure). Subsequent σ coordination of the benzoquinone oxygen atoms to added metal ions results in neutral one-, two-, or three-dimensional quinoid polymers. The geometrical requirements of the metal ion and the presence of added "spacer" ligands dictate the type of polymer formed.
AB - Coordination of Mn(CO)3+ to the π system in hydroquinone facilitates proton loss to afford benzoquinone complexes (see figure). Subsequent σ coordination of the benzoquinone oxygen atoms to added metal ions results in neutral one-, two-, or three-dimensional quinoid polymers. The geometrical requirements of the metal ion and the presence of added "spacer" ligands dictate the type of polymer formed.
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U2 - 10.1002/1521-3773(20010903)40:17<3191::AID-ANIE3191>3.0.CO;2-N
DO - 10.1002/1521-3773(20010903)40:17<3191::AID-ANIE3191>3.0.CO;2-N
M3 - Article
AN - SCOPUS:0035801521
VL - 40
SP - 3191
EP - 3194
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 17
ER -