Abstract
Coordination of Mn(CO)3+ to the π system in hydroquinone facilitates proton loss to afford benzoquinone complexes (see figure). Subsequent σ coordination of the benzoquinone oxygen atoms to added metal ions results in neutral one-, two-, or three-dimensional quinoid polymers. The geometrical requirements of the metal ion and the presence of added "spacer" ligands dictate the type of polymer formed.
| Original language | English |
|---|---|
| Pages (from-to) | 3191-3194 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 40 |
| Issue number | 17 |
| DOIs | |
| Publication status | Published - 2001 Sep 3 |
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All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)
Cite this
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Metal-mediated self-assembly of π-bonded benzoquinone complexes into polymers with tunable geometries. / Oh, Moonhyun; Carpenter, Gene B.; Sweigart, Dwight A.
In: Angewandte Chemie - International Edition, Vol. 40, No. 17, 03.09.2001, p. 3191-3194.Research output: Contribution to journal › Article
TY - JOUR
T1 - Metal-mediated self-assembly of π-bonded benzoquinone complexes into polymers with tunable geometries
AU - Oh, Moonhyun
AU - Carpenter, Gene B.
AU - Sweigart, Dwight A.
PY - 2001/9/3
Y1 - 2001/9/3
N2 - Coordination of Mn(CO)3+ to the π system in hydroquinone facilitates proton loss to afford benzoquinone complexes (see figure). Subsequent σ coordination of the benzoquinone oxygen atoms to added metal ions results in neutral one-, two-, or three-dimensional quinoid polymers. The geometrical requirements of the metal ion and the presence of added "spacer" ligands dictate the type of polymer formed.
AB - Coordination of Mn(CO)3+ to the π system in hydroquinone facilitates proton loss to afford benzoquinone complexes (see figure). Subsequent σ coordination of the benzoquinone oxygen atoms to added metal ions results in neutral one-, two-, or three-dimensional quinoid polymers. The geometrical requirements of the metal ion and the presence of added "spacer" ligands dictate the type of polymer formed.
UR - http://www.scopus.com/inward/record.url?scp=0035801521&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0035801521&partnerID=8YFLogxK
U2 - 10.1002/1521-3773(20010903)40:17<3191::AID-ANIE3191>3.0.CO;2-N
DO - 10.1002/1521-3773(20010903)40:17<3191::AID-ANIE3191>3.0.CO;2-N
M3 - Article
AN - SCOPUS:0035801521
VL - 40
SP - 3191
EP - 3194
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 17
ER -