Metal-organic frameworks with high working capacities and cyclic hydrothermal stabilities for fresh water production

Seung Ik Kim; Tae Ung Yoon; Min Bum Kim; Seung Joon Lee; Young Kyu Hwang; Jong San Chang; Hyun Jong Kim; Ho Nyun Lee; U. Hwang Lee; Youn Sang Bae

doi:10.1016/j.cej.2015.10.098

Metal-organic frameworks with high working capacities and cyclic hydrothermal stabilities for fresh water production

Seung Ik Kim, Tae Ung Yoon, Min Bum Kim, Seung Joon Lee, Young Kyu Hwang, Jong San Chang, Hyun Jong Kim, Ho Nyun Lee, U. Hwang Lee, Youn Sang Bae

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

In this work, we evaluated the working capacities of eight hydrothermally stable metal-organic frameworks (MOFs) for water adsorption under typical humidity conditions in three representative dry regions. Remarkably, three MIL-100(M) materials (M=Cr, Al, and Fe) and MIL-101(Cr) exhibited very high working capacities for medium and high humidity conditions due to their large surface areas. All of the MOFs consisting of only M^III sites (MIL-101(Cr), MIL-100(Cr), and MIL-100(Al)) showed good cyclic water adsorption/desorption performances and good hydrothermal stabilities. Due to the presence of Fe^II sites formed during activation at 250°C, MIL-100(Fe) showed a considerable decrease in its water adsorption isotherm during the 2nd cycle although almost unchanged water uptakes were observed in the following cycles. When MIL-100(Fe) was activated at 150°C (MIL-100(Fe)_150) to prevent formation of Fe^II sites, the sample showed good cyclic adsorption/desorption performance and good hydrothermal stability. Considering the high working capacities, cyclic adsorption/desorption behaviors, and good hydrothermal stabilities, MIL-101(Cr), MIL-100(Cr), MIL-100(Al) and MIL-100(Fe)_150 are promising adsorbents for producing drinking water in dry regions with medium or high humidity conditions during the night.

Original language	English
Pages (from-to)	467-475
Number of pages	9
Journal	Chemical Engineering Journal
Volume	286
DOIs	https://doi.org/10.1016/j.cej.2015.10.098
Publication status	Published - 2016 Feb 15

Bibliographical note

Funding Information:
This work was supported by the Technology Innovation Program ( 10048649 ) funded by the Ministry of Trade, Industry & Energy (MI, Korea). This research was also supported by the Pioneer Research Center Program through the National Research Foundation of Korea funded by the Ministry of Science, ICT & Future Planning ( NRF-2010-0019531 ).

All Science Journal Classification (ASJC) codes

Chemistry(all)
Environmental Chemistry
Chemical Engineering(all)
Industrial and Manufacturing Engineering

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@article{aca39db9d31844a9956b0f940b8d56ea,

title = "Metal-organic frameworks with high working capacities and cyclic hydrothermal stabilities for fresh water production",

abstract = "In this work, we evaluated the working capacities of eight hydrothermally stable metal-organic frameworks (MOFs) for water adsorption under typical humidity conditions in three representative dry regions. Remarkably, three MIL-100(M) materials (M=Cr, Al, and Fe) and MIL-101(Cr) exhibited very high working capacities for medium and high humidity conditions due to their large surface areas. All of the MOFs consisting of only MIII sites (MIL-101(Cr), MIL-100(Cr), and MIL-100(Al)) showed good cyclic water adsorption/desorption performances and good hydrothermal stabilities. Due to the presence of FeII sites formed during activation at 250°C, MIL-100(Fe) showed a considerable decrease in its water adsorption isotherm during the 2nd cycle although almost unchanged water uptakes were observed in the following cycles. When MIL-100(Fe) was activated at 150°C (MIL-100(Fe)_150) to prevent formation of FeII sites, the sample showed good cyclic adsorption/desorption performance and good hydrothermal stability. Considering the high working capacities, cyclic adsorption/desorption behaviors, and good hydrothermal stabilities, MIL-101(Cr), MIL-100(Cr), MIL-100(Al) and MIL-100(Fe)_150 are promising adsorbents for producing drinking water in dry regions with medium or high humidity conditions during the night.",

author = "Kim, {Seung Ik} and Yoon, {Tae Ung} and Kim, {Min Bum} and Lee, {Seung Joon} and Hwang, {Young Kyu} and Chang, {Jong San} and Kim, {Hyun Jong} and Lee, {Ho Nyun} and Lee, {U. Hwang} and Bae, {Youn Sang}",

note = "Funding Information: This work was supported by the Technology Innovation Program ( 10048649 ) funded by the Ministry of Trade, Industry & Energy (MI, Korea). This research was also supported by the Pioneer Research Center Program through the National Research Foundation of Korea funded by the Ministry of Science, ICT & Future Planning ( NRF-2010-0019531 ). ",

year = "2016",

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day = "15",

doi = "10.1016/j.cej.2015.10.098",

language = "English",

volume = "286",

pages = "467--475",

journal = "Chemical Engineering Journal",

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Metal-organic frameworks with high working capacities and cyclic hydrothermal stabilities for fresh water production. / Kim, Seung Ik; Yoon, Tae Ung; Kim, Min Bum; Lee, Seung Joon; Hwang, Young Kyu; Chang, Jong San; Kim, Hyun Jong; Lee, Ho Nyun; Lee, U. Hwang; Bae, Youn Sang.

In: Chemical Engineering Journal, Vol. 286, 15.02.2016, p. 467-475.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Metal-organic frameworks with high working capacities and cyclic hydrothermal stabilities for fresh water production

AU - Kim, Seung Ik

AU - Yoon, Tae Ung

AU - Kim, Min Bum

AU - Lee, Seung Joon

AU - Hwang, Young Kyu

AU - Chang, Jong San

AU - Kim, Hyun Jong

AU - Lee, Ho Nyun

AU - Lee, U. Hwang

AU - Bae, Youn Sang

N1 - Funding Information: This work was supported by the Technology Innovation Program ( 10048649 ) funded by the Ministry of Trade, Industry & Energy (MI, Korea). This research was also supported by the Pioneer Research Center Program through the National Research Foundation of Korea funded by the Ministry of Science, ICT & Future Planning ( NRF-2010-0019531 ).

PY - 2016/2/15

Y1 - 2016/2/15

N2 - In this work, we evaluated the working capacities of eight hydrothermally stable metal-organic frameworks (MOFs) for water adsorption under typical humidity conditions in three representative dry regions. Remarkably, three MIL-100(M) materials (M=Cr, Al, and Fe) and MIL-101(Cr) exhibited very high working capacities for medium and high humidity conditions due to their large surface areas. All of the MOFs consisting of only MIII sites (MIL-101(Cr), MIL-100(Cr), and MIL-100(Al)) showed good cyclic water adsorption/desorption performances and good hydrothermal stabilities. Due to the presence of FeII sites formed during activation at 250°C, MIL-100(Fe) showed a considerable decrease in its water adsorption isotherm during the 2nd cycle although almost unchanged water uptakes were observed in the following cycles. When MIL-100(Fe) was activated at 150°C (MIL-100(Fe)_150) to prevent formation of FeII sites, the sample showed good cyclic adsorption/desorption performance and good hydrothermal stability. Considering the high working capacities, cyclic adsorption/desorption behaviors, and good hydrothermal stabilities, MIL-101(Cr), MIL-100(Cr), MIL-100(Al) and MIL-100(Fe)_150 are promising adsorbents for producing drinking water in dry regions with medium or high humidity conditions during the night.

AB - In this work, we evaluated the working capacities of eight hydrothermally stable metal-organic frameworks (MOFs) for water adsorption under typical humidity conditions in three representative dry regions. Remarkably, three MIL-100(M) materials (M=Cr, Al, and Fe) and MIL-101(Cr) exhibited very high working capacities for medium and high humidity conditions due to their large surface areas. All of the MOFs consisting of only MIII sites (MIL-101(Cr), MIL-100(Cr), and MIL-100(Al)) showed good cyclic water adsorption/desorption performances and good hydrothermal stabilities. Due to the presence of FeII sites formed during activation at 250°C, MIL-100(Fe) showed a considerable decrease in its water adsorption isotherm during the 2nd cycle although almost unchanged water uptakes were observed in the following cycles. When MIL-100(Fe) was activated at 150°C (MIL-100(Fe)_150) to prevent formation of FeII sites, the sample showed good cyclic adsorption/desorption performance and good hydrothermal stability. Considering the high working capacities, cyclic adsorption/desorption behaviors, and good hydrothermal stabilities, MIL-101(Cr), MIL-100(Cr), MIL-100(Al) and MIL-100(Fe)_150 are promising adsorbents for producing drinking water in dry regions with medium or high humidity conditions during the night.

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