Metal Phosphorous Trichalcogenides (MPCh3): From Synthesis to Contemporary Energy Challenges

Rui Gusmão, Zdenek Sofer, Martin Pumera

Research output: Contribution to journalReview articlepeer-review

57 Citations (Scopus)


Owing to their unique physical and chemical properties, layered two-dimensional (2D) materials have been established as the most significant topic in materials science for the current decade. This includes layers comprising mono-element (graphene, phosphorene), di-element (metal dichalcogenides), and even multi-element. A distinctive class of 2D layered materials is the metal phosphorous trichalcogenides (MPCh3, Ch=S, Se), first synthesized in the late 1800s. Having an unusual intercalation behavior, MPCh3 were intensively studied in the 1970s for their magnetic properties and as secondary electrodes in lithium batteries, but fell from scrutiny until very recently, being 2D nanomaterials. Based on their synthesis and most significant properties, the present surge of reports related to water-splitting catalysis and energy storage are discussed in detail. This Minireview is intended as a baseline for the anticipated new wave of researchers who aim to explore these 2D layered materials for their electrochemical energy applications.

Original languageEnglish
Pages (from-to)9326-9337
Number of pages12
JournalAngewandte Chemie - International Edition
Issue number28
Publication statusPublished - 2019 Jul 8

Bibliographical note

Funding Information:
Z.S. is supported by Czech Science Foundation (GACR No. 17-11456S). This work was created with the financial support of the Neuron Foundation for science support and the Advanced Functional Nanorobots project (reg. No. CZ.02.1.01/0.0/0.0/15_003/0000444 financed by the EFRR).

Publisher Copyright:
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)


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