Metalation of expanded porphyrins

A chemical trigger used to produce molecular twisting and Möbius aromaticity

Yasuo Tanaka, Shohei Saito, Shigeki Mori, Naoki Aratani, Hiroshi Shinokubo, Naoki Shibata, Yoshiki Higuchi, Zin Seok Yoon, Kil Suk Kim, Su Bum Noh, Jong Kang Park, Dongho Kim, Atsuhiro Osuka

Research output: Contribution to journalArticle

208 Citations (Scopus)

Abstract

(Chemical Equation Presented) Round the twist: Metalation of [36]octaphyrin 1 provided the Möbius aromatic Pd2 complex 3 as well as the Hückel antiaromatic Pd2 complex 2. This method can be applied to other expanded porphyrins and Group 10 metal ions. The aromatic/antiaromatic character was supported by NMR spectrscopy, NICS calculation, and two-photon absorption measurements.

Original languageEnglish
Pages (from-to)681-684
Number of pages4
JournalAngewandte Chemie - International Edition
Volume47
Issue number4
DOIs
Publication statusPublished - 2008 Jan 24

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Porphyrins
Metal ions
Photons
Nuclear magnetic resonance

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Tanaka, Yasuo ; Saito, Shohei ; Mori, Shigeki ; Aratani, Naoki ; Shinokubo, Hiroshi ; Shibata, Naoki ; Higuchi, Yoshiki ; Yoon, Zin Seok ; Kim, Kil Suk ; Noh, Su Bum ; Park, Jong Kang ; Kim, Dongho ; Osuka, Atsuhiro. / Metalation of expanded porphyrins : A chemical trigger used to produce molecular twisting and Möbius aromaticity. In: Angewandte Chemie - International Edition. 2008 ; Vol. 47, No. 4. pp. 681-684.
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author = "Yasuo Tanaka and Shohei Saito and Shigeki Mori and Naoki Aratani and Hiroshi Shinokubo and Naoki Shibata and Yoshiki Higuchi and Yoon, {Zin Seok} and Kim, {Kil Suk} and Noh, {Su Bum} and Park, {Jong Kang} and Dongho Kim and Atsuhiro Osuka",
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doi = "10.1002/anie.200704407",
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Tanaka, Y, Saito, S, Mori, S, Aratani, N, Shinokubo, H, Shibata, N, Higuchi, Y, Yoon, ZS, Kim, KS, Noh, SB, Park, JK, Kim, D & Osuka, A 2008, 'Metalation of expanded porphyrins: A chemical trigger used to produce molecular twisting and Möbius aromaticity', Angewandte Chemie - International Edition, vol. 47, no. 4, pp. 681-684. https://doi.org/10.1002/anie.200704407

Metalation of expanded porphyrins : A chemical trigger used to produce molecular twisting and Möbius aromaticity. / Tanaka, Yasuo; Saito, Shohei; Mori, Shigeki; Aratani, Naoki; Shinokubo, Hiroshi; Shibata, Naoki; Higuchi, Yoshiki; Yoon, Zin Seok; Kim, Kil Suk; Noh, Su Bum; Park, Jong Kang; Kim, Dongho; Osuka, Atsuhiro.

In: Angewandte Chemie - International Edition, Vol. 47, No. 4, 24.01.2008, p. 681-684.

Research output: Contribution to journalArticle

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T1 - Metalation of expanded porphyrins

T2 - A chemical trigger used to produce molecular twisting and Möbius aromaticity

AU - Tanaka, Yasuo

AU - Saito, Shohei

AU - Mori, Shigeki

AU - Aratani, Naoki

AU - Shinokubo, Hiroshi

AU - Shibata, Naoki

AU - Higuchi, Yoshiki

AU - Yoon, Zin Seok

AU - Kim, Kil Suk

AU - Noh, Su Bum

AU - Park, Jong Kang

AU - Kim, Dongho

AU - Osuka, Atsuhiro

PY - 2008/1/24

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