Abstract
The characteristics of micelle formed in blends of styrene-isoprene diblock copolymer (SI) and poly(vinyl methyl ether) (PVME) were investigated by using small-angle X-ray scattering (SAXS), transmission electron microscopy (TEM), and light scattering techniques. The results of SAXS and TEM experiments indicate that the blends form spherical micelles with isoprene-rich cores and styrene-corona mixed with PVME in a matrix of PVME. As temperature increased, the blends underwent macrophase separation into a PVME-rich phase and a SI-rich phase which was also microphase-separated to ordered microdomains. Upon further heating, the ordered structure of the SI-rich region transforms to a disordered phase in a manner resembling the order-disorder transition in pure block copolymer melts.
| Original language | English |
|---|---|
| Pages (from-to) | 4459-4465 |
| Number of pages | 7 |
| Journal | Macromolecules |
| Volume | 34 |
| Issue number | 13 |
| DOIs | |
| Publication status | Published - 2001 Jun 19 |
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All Science Journal Classification (ASJC) codes
- Organic Chemistry
- Polymers and Plastics
- Inorganic Chemistry
- Materials Chemistry
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Micelle formation in mixtures of styrene-isoprene diblock copolymer and poly(vinyl methyl ether). / Ahn, Jong-Hyun; Sohn, Byeong Hyeok; Zin, Wang Cheol; Noh, Si Tae.
In: Macromolecules, Vol. 34, No. 13, 19.06.2001, p. 4459-4465.Research output: Contribution to journal › Article
TY - JOUR
T1 - Micelle formation in mixtures of styrene-isoprene diblock copolymer and poly(vinyl methyl ether)
AU - Ahn, Jong-Hyun
AU - Sohn, Byeong Hyeok
AU - Zin, Wang Cheol
AU - Noh, Si Tae
PY - 2001/6/19
Y1 - 2001/6/19
N2 - The characteristics of micelle formed in blends of styrene-isoprene diblock copolymer (SI) and poly(vinyl methyl ether) (PVME) were investigated by using small-angle X-ray scattering (SAXS), transmission electron microscopy (TEM), and light scattering techniques. The results of SAXS and TEM experiments indicate that the blends form spherical micelles with isoprene-rich cores and styrene-corona mixed with PVME in a matrix of PVME. As temperature increased, the blends underwent macrophase separation into a PVME-rich phase and a SI-rich phase which was also microphase-separated to ordered microdomains. Upon further heating, the ordered structure of the SI-rich region transforms to a disordered phase in a manner resembling the order-disorder transition in pure block copolymer melts.
AB - The characteristics of micelle formed in blends of styrene-isoprene diblock copolymer (SI) and poly(vinyl methyl ether) (PVME) were investigated by using small-angle X-ray scattering (SAXS), transmission electron microscopy (TEM), and light scattering techniques. The results of SAXS and TEM experiments indicate that the blends form spherical micelles with isoprene-rich cores and styrene-corona mixed with PVME in a matrix of PVME. As temperature increased, the blends underwent macrophase separation into a PVME-rich phase and a SI-rich phase which was also microphase-separated to ordered microdomains. Upon further heating, the ordered structure of the SI-rich region transforms to a disordered phase in a manner resembling the order-disorder transition in pure block copolymer melts.
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U2 - 10.1021/ma001642+
DO - 10.1021/ma001642+
M3 - Article
AN - SCOPUS:0035912999
VL - 34
SP - 4459
EP - 4465
JO - Macromolecules
JF - Macromolecules
SN - 0024-9297
IS - 13
ER -