Abstract
Al2O3 changes from transparent to a range of intense colours depending on the chemical impurities present. In blue sapphire, Fe and Ti are incorporated; however, the chemical process that gives rise to the colour has long been debated. Atomistic modelling identifies charge transfer from Ti(iii) to Fe(iii) as being responsible for the characteristic blue appearance.
| Original language | English |
|---|---|
| Pages (from-to) | 5259-5261 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 49 |
| Issue number | 46 |
| DOIs | |
| Publication status | Published - 2013 Jun 11 |
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All Science Journal Classification (ASJC) codes
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
Cite this
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Microscopic origin of the optical processes in blue sapphire. / Bristow, Jessica K.; Parker, Stephen C.; A. Catlow, C. Richard; Woodley, Scott M.; Walsh, Aron.
In: Chemical Communications, Vol. 49, No. 46, 11.06.2013, p. 5259-5261.Research output: Contribution to journal › Article
TY - JOUR
T1 - Microscopic origin of the optical processes in blue sapphire
AU - Bristow, Jessica K.
AU - Parker, Stephen C.
AU - A. Catlow, C. Richard
AU - Woodley, Scott M.
AU - Walsh, Aron
PY - 2013/6/11
Y1 - 2013/6/11
N2 - Al2O3 changes from transparent to a range of intense colours depending on the chemical impurities present. In blue sapphire, Fe and Ti are incorporated; however, the chemical process that gives rise to the colour has long been debated. Atomistic modelling identifies charge transfer from Ti(iii) to Fe(iii) as being responsible for the characteristic blue appearance.
AB - Al2O3 changes from transparent to a range of intense colours depending on the chemical impurities present. In blue sapphire, Fe and Ti are incorporated; however, the chemical process that gives rise to the colour has long been debated. Atomistic modelling identifies charge transfer from Ti(iii) to Fe(iii) as being responsible for the characteristic blue appearance.
UR - http://www.scopus.com/inward/record.url?scp=84877768524&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84877768524&partnerID=8YFLogxK
U2 - 10.1039/c3cc41506f
DO - 10.1039/c3cc41506f
M3 - Article
C2 - 23632734
AN - SCOPUS:84877768524
VL - 49
SP - 5259
EP - 5261
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 46
ER -