Microwave synthesis of hybrid inorganic-organic materials including porous Cu3(BTC)2 from Cu(II)-trimesate mixture

You Kyong Seo, Geeta Hundal, In Tae Jang, Young Kyu Hwang, Chul Ho Jun, Jong San Chang

Research output: Contribution to journalArticle

191 Citations (Scopus)

Abstract

Using a single, improved synthetic process, three different compounds comprising two known phases such as [Cu3(BTC)2(H2O)3] (1), [Cu2(OH)(BTC)(H2O)] · 2nH2O (2) and a new phase [Cu(BTC-H2)2-(H2O)2] · 3H2O (3) have been prepared by microwave-irradiation (MW) of identical reaction mixture of Cu(II) salt and trimesic acid, benzene-1,3,5-tricarboxylic acid (BTC-H3) at different temperatures. The microwave synthesis of (1) has been compared to its conventional hydrothermal synthesis. It has been found that by using MW synthesis (1) can be obtained in a much shorter synthesis time with improved yield and physical properties. The effect of other synthetic parameters such as solvent, concentration of reactant mixtures and reaction time on the product (1) has been also studied. At high temperature, the compound (2) was obtained in the same solution. The new phase (3) has been characterized by elemental analysis, thermogravimetric analysis, IR spectroscopy, scanning electron microscopy and powder XRD analysis.

Original languageEnglish
Pages (from-to)331-337
Number of pages7
JournalMicroporous and Mesoporous Materials
Volume119
Issue number1-3
DOIs
Publication statusPublished - 2009 Mar 1

Fingerprint

organic materials
Porous materials
Microwave irradiation
Microwaves
microwaves
synthesis
Tricarboxylic Acids
Acids
Hydrothermal synthesis
Benzene
Powders
acids
irradiation
Thermogravimetric analysis
Infrared spectroscopy
Physical properties
Salts
reaction time
Temperature
Scanning electron microscopy

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials

Cite this

Seo, You Kyong ; Hundal, Geeta ; Jang, In Tae ; Hwang, Young Kyu ; Jun, Chul Ho ; Chang, Jong San. / Microwave synthesis of hybrid inorganic-organic materials including porous Cu3(BTC)2 from Cu(II)-trimesate mixture. In: Microporous and Mesoporous Materials. 2009 ; Vol. 119, No. 1-3. pp. 331-337.
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Microwave synthesis of hybrid inorganic-organic materials including porous Cu3(BTC)2 from Cu(II)-trimesate mixture. / Seo, You Kyong; Hundal, Geeta; Jang, In Tae; Hwang, Young Kyu; Jun, Chul Ho; Chang, Jong San.

In: Microporous and Mesoporous Materials, Vol. 119, No. 1-3, 01.03.2009, p. 331-337.

Research output: Contribution to journalArticle

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