Microwave synthesis of hybrid inorganic-organic materials including porous Cu3(BTC)2 from Cu(II)-trimesate mixture

You Kyong Seo; Geeta Hundal; In Tae Jang; Young Kyu Hwang; Chul Ho Jun; Jong San Chang

doi:10.1016/j.micromeso.2008.10.035

Microwave synthesis of hybrid inorganic-organic materials including porous Cu₃(BTC)₂ from Cu(II)-trimesate mixture

You Kyong Seo, Geeta Hundal, In Tae Jang, Young Kyu Hwang, Chul Ho Jun, Jong San Chang

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

216 Citations (Scopus)

Abstract

Using a single, improved synthetic process, three different compounds comprising two known phases such as [Cu₃(BTC)₂(H₂O)₃] (1), [Cu₂(OH)(BTC)(H₂O)] · 2nH₂O (2) and a new phase [Cu(BTC-H₂)₂-(H₂O)₂] · 3H₂O (3) have been prepared by microwave-irradiation (MW) of identical reaction mixture of Cu(II) salt and trimesic acid, benzene-1,3,5-tricarboxylic acid (BTC-H₃) at different temperatures. The microwave synthesis of (1) has been compared to its conventional hydrothermal synthesis. It has been found that by using MW synthesis (1) can be obtained in a much shorter synthesis time with improved yield and physical properties. The effect of other synthetic parameters such as solvent, concentration of reactant mixtures and reaction time on the product (1) has been also studied. At high temperature, the compound (2) was obtained in the same solution. The new phase (3) has been characterized by elemental analysis, thermogravimetric analysis, IR spectroscopy, scanning electron microscopy and powder XRD analysis.

Original language	English
Pages (from-to)	331-337
Number of pages	7
Journal	Microporous and Mesoporous Materials
Volume	119
Issue number	1-3
DOIs	https://doi.org/10.1016/j.micromeso.2008.10.035
Publication status	Published - 2009 Mar 1

Bibliographical note

Funding Information:
This work was supported by MKE through the Research Center for Nanocatalysts and Institutional Research Program. Dr. Geeta Hundal gratefully acknowledges KOFST for awarding the Brain Pool fellowship at KRICT, Korea.

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics
Mechanics of Materials

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title = "Microwave synthesis of hybrid inorganic-organic materials including porous Cu3(BTC)2 from Cu(II)-trimesate mixture",

abstract = "Using a single, improved synthetic process, three different compounds comprising two known phases such as [Cu3(BTC)2(H2O)3] (1), [Cu2(OH)(BTC)(H2O)] · 2nH2O (2) and a new phase [Cu(BTC-H2)2-(H2O)2] · 3H2O (3) have been prepared by microwave-irradiation (MW) of identical reaction mixture of Cu(II) salt and trimesic acid, benzene-1,3,5-tricarboxylic acid (BTC-H3) at different temperatures. The microwave synthesis of (1) has been compared to its conventional hydrothermal synthesis. It has been found that by using MW synthesis (1) can be obtained in a much shorter synthesis time with improved yield and physical properties. The effect of other synthetic parameters such as solvent, concentration of reactant mixtures and reaction time on the product (1) has been also studied. At high temperature, the compound (2) was obtained in the same solution. The new phase (3) has been characterized by elemental analysis, thermogravimetric analysis, IR spectroscopy, scanning electron microscopy and powder XRD analysis.",

author = "Seo, {You Kyong} and Geeta Hundal and Jang, {In Tae} and Hwang, {Young Kyu} and Jun, {Chul Ho} and Chang, {Jong San}",

note = "Funding Information: This work was supported by MKE through the Research Center for Nanocatalysts and Institutional Research Program. Dr. Geeta Hundal gratefully acknowledges KOFST for awarding the Brain Pool fellowship at KRICT, Korea.",

year = "2009",

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doi = "10.1016/j.micromeso.2008.10.035",

language = "English",

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T1 - Microwave synthesis of hybrid inorganic-organic materials including porous Cu3(BTC)2 from Cu(II)-trimesate mixture

AU - Seo, You Kyong

AU - Hundal, Geeta

AU - Jang, In Tae

AU - Hwang, Young Kyu

AU - Jun, Chul Ho

AU - Chang, Jong San

N1 - Funding Information: This work was supported by MKE through the Research Center for Nanocatalysts and Institutional Research Program. Dr. Geeta Hundal gratefully acknowledges KOFST for awarding the Brain Pool fellowship at KRICT, Korea.

PY - 2009/3/1

Y1 - 2009/3/1

N2 - Using a single, improved synthetic process, three different compounds comprising two known phases such as [Cu3(BTC)2(H2O)3] (1), [Cu2(OH)(BTC)(H2O)] · 2nH2O (2) and a new phase [Cu(BTC-H2)2-(H2O)2] · 3H2O (3) have been prepared by microwave-irradiation (MW) of identical reaction mixture of Cu(II) salt and trimesic acid, benzene-1,3,5-tricarboxylic acid (BTC-H3) at different temperatures. The microwave synthesis of (1) has been compared to its conventional hydrothermal synthesis. It has been found that by using MW synthesis (1) can be obtained in a much shorter synthesis time with improved yield and physical properties. The effect of other synthetic parameters such as solvent, concentration of reactant mixtures and reaction time on the product (1) has been also studied. At high temperature, the compound (2) was obtained in the same solution. The new phase (3) has been characterized by elemental analysis, thermogravimetric analysis, IR spectroscopy, scanning electron microscopy and powder XRD analysis.

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