Million-fold electrical conductivity enhancement in Fe2(DEBDC) versus Mn2(DEBDC) (E = S, O)

Lei Sun, Christopher H. Hendon, Mikael A. Minier, Aron Walsh, Mircea Dincə

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132 Citations (Scopus)

Abstract

Reaction of FeCl2 and H4DSBDC (2,5-disulfhydrylbenzene-1,4-dicarboxylic acid) leads to the formation of Fe2(DSBDC), an analogue of M2(DOBDC) (MOF-74, DOBDC4- = 2,5-dihydroxybenzene-1,4-dicarboxylate). The bulk electrical conductivity values of both Fe2(DSBDC) and Fe2(DOBDC) are ~6 orders of magnitude higher than those of the Mn2+ analogues, Mn2(DEBDC) (E = O, S). Because the metals are of the same formal oxidation state, the increase in conductivity is attributed to the loosely bound Fe2+ β-spin electron. These results provide important insight for the rational design of conductive metal-organic frameworks, highlighting in particular the advantages of iron for synthesizing such materials.

Original languageEnglish
Pages (from-to)6164-6167
Number of pages4
JournalJournal of the American Chemical Society
Volume137
Issue number19
DOIs
Publication statusPublished - 2015 May 20

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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