Minireview: Selective production of hydrogen peroxide as a clean oxidant over structurally tailored carbon nitride photocatalysts

Zeeshan Haider, Hae in Cho, Gun hee Moon, Hyoung il Kim

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Hydrogen peroxide (H2O2) is a clean oxidant, and its demand has continuously risen in various industries for pulp/paper bleaching, chemical synthesis, wastewater treatment, etc. H2O2 is commercially produced by the anthraquinone method, which has some drawbacks, including (i) toxic solvent, (ii) explosive hydrogen gas as a precursor, and (iii) a high energy input; therefore, a new technology based on cost-effective and green processes is required. Photocatalytic production of H2O2 can be considered the most environmentally benign and economically feasible process because it requires only dissolved oxygen, water, and sunlight. Among various photocatalysts, polymeric carbon nitride (C3N4) is a promising candidate for H2O2 production by virtue of its (i) simple synthesis by a thermal polymerization, (ii) structure consisting of earth-abundant carbon and nitrogen, (iii) effective bandgap size for visible light absorption, and (iv) suitable position of conduction band for reduction of oxygen dissolved in water. In this minireview, the mechanism of H2O2 formation over C3N4 has been discussed, and the strategies to optimize the photocatalytic activity have been summarized regarding structural and surface modification techniques. This overview of diverse methodologies to selectively control electron transfer to dissolved oxygen should be in demand not only for developing new-generation C3N4-based materials, but also for commercialization of solar-light-driven photocatalytic H2O2 production system.

Original languageEnglish
Pages (from-to)55-64
Number of pages10
JournalCatalysis Today
Volume335
DOIs
Publication statusPublished - 2019 Sep 1

Fingerprint

Carbon nitride
Dissolved oxygen
Photocatalysts
Oxidants
Hydrogen peroxide
Hydrogen Peroxide
Anthraquinones
Water
Poisons
Bleaching
Conduction bands
Wastewater treatment
Light absorption
Pulp
Surface treatment
Hydrogen
Energy gap
Nitrogen
Carbon
Gases

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

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title = "Minireview: Selective production of hydrogen peroxide as a clean oxidant over structurally tailored carbon nitride photocatalysts",
abstract = "Hydrogen peroxide (H2O2) is a clean oxidant, and its demand has continuously risen in various industries for pulp/paper bleaching, chemical synthesis, wastewater treatment, etc. H2O2 is commercially produced by the anthraquinone method, which has some drawbacks, including (i) toxic solvent, (ii) explosive hydrogen gas as a precursor, and (iii) a high energy input; therefore, a new technology based on cost-effective and green processes is required. Photocatalytic production of H2O2 can be considered the most environmentally benign and economically feasible process because it requires only dissolved oxygen, water, and sunlight. Among various photocatalysts, polymeric carbon nitride (C3N4) is a promising candidate for H2O2 production by virtue of its (i) simple synthesis by a thermal polymerization, (ii) structure consisting of earth-abundant carbon and nitrogen, (iii) effective bandgap size for visible light absorption, and (iv) suitable position of conduction band for reduction of oxygen dissolved in water. In this minireview, the mechanism of H2O2 formation over C3N4 has been discussed, and the strategies to optimize the photocatalytic activity have been summarized regarding structural and surface modification techniques. This overview of diverse methodologies to selectively control electron transfer to dissolved oxygen should be in demand not only for developing new-generation C3N4-based materials, but also for commercialization of solar-light-driven photocatalytic H2O2 production system.",
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Minireview : Selective production of hydrogen peroxide as a clean oxidant over structurally tailored carbon nitride photocatalysts. / Haider, Zeeshan; Cho, Hae in; Moon, Gun hee; Kim, Hyoung il.

In: Catalysis Today, Vol. 335, 01.09.2019, p. 55-64.

Research output: Contribution to journalArticle

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