TY - JOUR
T1 - Modification of polybutadiene by transition metal catalysts
T2 - Hydroacylation of polybutadiene
AU - Jun, Chul Ho
AU - Lee, Hyuk
AU - Hong, Jun Bae
AU - Lee, Dae Yon
PY - 2000
Y1 - 2000
N2 - The vinyl groups in polybutadiene are hydroacylated in the presence of a transition metal complex to give acylfunctionalized polybutadiene. Aldimine, aldehyde, and primary alcohol can be used for hydroacylation as substrates. It is noteworthy that the hydrogenation of double bonds as well as hydroacylation are achieved when primary alcohol is used. A variety of functional groups, including acylferrocenyl, benzoyl and acylheteroaromatic, are incorporated into the polymer backbone. The modified polymers are characterized by 1H NMR, 13C NMR, and IR spectroscopy. The brief overviews on the other modification methods are also presented.
AB - The vinyl groups in polybutadiene are hydroacylated in the presence of a transition metal complex to give acylfunctionalized polybutadiene. Aldimine, aldehyde, and primary alcohol can be used for hydroacylation as substrates. It is noteworthy that the hydrogenation of double bonds as well as hydroacylation are achieved when primary alcohol is used. A variety of functional groups, including acylferrocenyl, benzoyl and acylheteroaromatic, are incorporated into the polymer backbone. The modified polymers are characterized by 1H NMR, 13C NMR, and IR spectroscopy. The brief overviews on the other modification methods are also presented.
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M3 - Article
AN - SCOPUS:0042916296
VL - 760
SP - 94
EP - 107
JO - ACS Symposium Series
JF - ACS Symposium Series
SN - 0097-6156
ER -