Modification of polyol process for synthesis of highly platinum loaded platinum-carbon catalysts for fuel cells

Hyung Suk Oh, Jong Gil Oh, Hansung Kim

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

A modified polyol process is developed to enhance the Pt loading during the preparation of carbon-supported platinum (Pt/C) catalysts. With the help of the zeta potential, the effect of pH on the electrostatic forces between the support and the Pt colloid is investigated. It is shown experimentally that the surface charge on the carbon support becomes more electropositive when the solution pH is changed from alkaline to acidic. This change does not, however, affect the electronegative surface charge of Pt colloids already attained and stabilized by glycolate anions. This new behaviour caused by the change in solution pH accounts for the enhanced yield of the process and does not affect the Pt particle size. All the experimental results reveal that this simple modification is a cost-effective method for the synthesis of highly Pt-loaded Pt/C catalysts for fuel cells.

Original languageEnglish
Pages (from-to)600-603
Number of pages4
JournalJournal of Power Sources
Volume183
Issue number2
DOIs
Publication statusPublished - 2008 Sep 1

Fingerprint

glycolic acid
Polyols
Colloids
Surface charge
Platinum
fuel cells
Fuel cells
platinum
Carbon
catalysts
Catalysts
colloids
Electrostatic force
carbon
Zeta potential
synthesis
Anions
Negative ions
Particle size
electrostatics

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

Cite this

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Modification of polyol process for synthesis of highly platinum loaded platinum-carbon catalysts for fuel cells. / Oh, Hyung Suk; Oh, Jong Gil; Kim, Hansung.

In: Journal of Power Sources, Vol. 183, No. 2, 01.09.2008, p. 600-603.

Research output: Contribution to journalArticle

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