TY - JOUR
T1 - Modulation of dual electronic circuits of [26]hexaphyrins using internal aromatic straps
AU - Mori, Hirotaka
AU - Lim, Jong Min
AU - Kim, Dongho
AU - Osuka, Atsuhiro
PY - 2013/12/2
Y1 - 2013/12/2
N2 - Internal bridges: [26]Hexaphyrins with an aromatic strap in 5,20 position have two potentially cyclic conjugated networks, that is, [18]porphyrin and [26]hexaphyrin (see picture), and show a formal analogy with [18]annuleno[18]annulens. 1,3-Phenylene-, 2,5-thienylene-, and 2,5-pyrrylene-bridged [26]hexaphyrins have been synthesized and characterized.
AB - Internal bridges: [26]Hexaphyrins with an aromatic strap in 5,20 position have two potentially cyclic conjugated networks, that is, [18]porphyrin and [26]hexaphyrin (see picture), and show a formal analogy with [18]annuleno[18]annulens. 1,3-Phenylene-, 2,5-thienylene-, and 2,5-pyrrylene-bridged [26]hexaphyrins have been synthesized and characterized.
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U2 - 10.1002/anie.201308545
DO - 10.1002/anie.201308545
M3 - Article
C2 - 24218297
AN - SCOPUS:84888597703
SN - 1433-7851
VL - 52
SP - 12997
EP - 13001
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 49
ER -