Monolithically integrated, photo-rechargeable portable power sources based on miniaturized Si solar cells and printed solid-state lithium-ion batteries

Han Don Um, Keun Ho Choi, Inchan Hwang, Se Hee Kim, Kwanyong Seo, Sang Young Lee

Research output: Contribution to journalArticlepeer-review

46 Citations (Scopus)

Abstract

The combination of energy generation and energy storage systems is the ultimate solution to meet the ever-increasing demand for high-energy-density power sources. Here, we demonstrate a new class of monolithically integrated, photo-rechargeable portable power sources based on miniaturized crystalline Si photovoltaics (c-Si PVs) and printed solid-state lithium-ion batteries (LIBs). A solid-state LIB with a bipolar cell configuration is fabricated directly on the aluminium electrode of a c-Si PV module through an in-series printing process, which enables the seamless architectural/electrical connection of the two different energy systems. The single-unit PV-LIB device shows exceptional electrochemical performance that lies far beyond those achievable by conventional PVs or LIBs alone: it displays fast, low-light-intensity and high-temperature photo-charging; a photo-electric conversion/storage efficiency of 7.61%; a sustainable cycling performance; and continuous discharging at an extremely high current density of 28C under sunlight illumination. This study opens a facile and scalable route for the development of single-unit, photo-rechargeable mobile high-performance batteries that are required for the future era of ubiquitous electronics.

Original languageEnglish
Pages (from-to)931-940
Number of pages10
JournalEnergy and Environmental Science
Volume10
Issue number4
DOIs
Publication statusPublished - 2017 Apr

Bibliographical note

Funding Information:
This work was supported by the Basic Research Program (2014R1A1A1004885, 2015R1D1A1A01059726, 2015R1A2A1A01003474) and the Wearable Platform Materials Technology Center (2016R1A5A1009926) through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT & Future Planning. This work was also supported by the Development Program of the Korea Institute of Energy Research (KIER) (Grant No. B6-2431).

All Science Journal Classification (ASJC) codes

  • Environmental Chemistry
  • Renewable Energy, Sustainability and the Environment
  • Nuclear Energy and Engineering
  • Pollution

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