The combination of energy generation and energy storage systems is the ultimate solution to meet the ever-increasing demand for high-energy-density power sources. Here, we demonstrate a new class of monolithically integrated, photo-rechargeable portable power sources based on miniaturized crystalline Si photovoltaics (c-Si PVs) and printed solid-state lithium-ion batteries (LIBs). A solid-state LIB with a bipolar cell configuration is fabricated directly on the aluminium electrode of a c-Si PV module through an in-series printing process, which enables the seamless architectural/electrical connection of the two different energy systems. The single-unit PV-LIB device shows exceptional electrochemical performance that lies far beyond those achievable by conventional PVs or LIBs alone: it displays fast, low-light-intensity and high-temperature photo-charging; a photo-electric conversion/storage efficiency of 7.61%; a sustainable cycling performance; and continuous discharging at an extremely high current density of 28C under sunlight illumination. This study opens a facile and scalable route for the development of single-unit, photo-rechargeable mobile high-performance batteries that are required for the future era of ubiquitous electronics.
Bibliographical noteFunding Information:
This work was supported by the Basic Research Program (2014R1A1A1004885, 2015R1D1A1A01059726, 2015R1A2A1A01003474) and the Wearable Platform Materials Technology Center (2016R1A5A1009926) through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT & Future Planning. This work was also supported by the Development Program of the Korea Institute of Energy Research (KIER) (Grant No. B6-2431).
© The Royal Society of Chemistry 2017.
All Science Journal Classification (ASJC) codes
- Environmental Chemistry
- Renewable Energy, Sustainability and the Environment
- Nuclear Energy and Engineering