Abstract
The selective formation of coordination polymer particles (CPPs) with diverse shapes from the same basic building blocks namely elongated hexagons, ellipsoids, and rods, was reported. A carbonyl-functionalized ligand was synthesized with slight changes. CPPs were prepared by the solvothermal reactions, where H2L, In(NO3)3. xH 2O, imidazole, and CH3CO2H were combined in dimethylformamide (DMF). The morphology of the resulting product was characterized by field-emission Scanning Electron microscopy (SEM), Optical Microscopy (OM), and Fluorescence Microscopy (FM). The images reveal the formation of elongated hexagonal particles, with an average width and length of 1.52 and 3.00μm. It was also observed that the diversely-shaped CPPs have different gas-adsorption properties for several gas molecules, even though they have the same components.
| Original language | English |
|---|---|
| Pages (from-to) | 674-677 |
| Number of pages | 4 |
| Journal | Advanced Materials |
| Volume | 21 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - 2009 Feb 9 |
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All Science Journal Classification (ASJC) codes
- Materials Science(all)
- Mechanics of Materials
- Mechanical Engineering
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Morphology-selective formation and morphology-dependent gas-adsorption properties of coordination polymer particles. / Lee, Hee Jung; Cho, Won; Jung, Soyoung; Oh, Moonhyun.
In: Advanced Materials, Vol. 21, No. 6, 09.02.2009, p. 674-677.Research output: Contribution to journal › Article
TY - JOUR
T1 - Morphology-selective formation and morphology-dependent gas-adsorption properties of coordination polymer particles
AU - Lee, Hee Jung
AU - Cho, Won
AU - Jung, Soyoung
AU - Oh, Moonhyun
PY - 2009/2/9
Y1 - 2009/2/9
N2 - The selective formation of coordination polymer particles (CPPs) with diverse shapes from the same basic building blocks namely elongated hexagons, ellipsoids, and rods, was reported. A carbonyl-functionalized ligand was synthesized with slight changes. CPPs were prepared by the solvothermal reactions, where H2L, In(NO3)3. xH 2O, imidazole, and CH3CO2H were combined in dimethylformamide (DMF). The morphology of the resulting product was characterized by field-emission Scanning Electron microscopy (SEM), Optical Microscopy (OM), and Fluorescence Microscopy (FM). The images reveal the formation of elongated hexagonal particles, with an average width and length of 1.52 and 3.00μm. It was also observed that the diversely-shaped CPPs have different gas-adsorption properties for several gas molecules, even though they have the same components.
AB - The selective formation of coordination polymer particles (CPPs) with diverse shapes from the same basic building blocks namely elongated hexagons, ellipsoids, and rods, was reported. A carbonyl-functionalized ligand was synthesized with slight changes. CPPs were prepared by the solvothermal reactions, where H2L, In(NO3)3. xH 2O, imidazole, and CH3CO2H were combined in dimethylformamide (DMF). The morphology of the resulting product was characterized by field-emission Scanning Electron microscopy (SEM), Optical Microscopy (OM), and Fluorescence Microscopy (FM). The images reveal the formation of elongated hexagonal particles, with an average width and length of 1.52 and 3.00μm. It was also observed that the diversely-shaped CPPs have different gas-adsorption properties for several gas molecules, even though they have the same components.
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U2 - 10.1002/adma.200802485
DO - 10.1002/adma.200802485
M3 - Article
AN - SCOPUS:60349087362
VL - 21
SP - 674
EP - 677
JO - Advanced Materials
JF - Advanced Materials
SN - 0935-9648
IS - 6
ER -