Multi-color fluorescence switching with electrofluorochromic polymers

Hanwhuy Lim, Seogjae Seo, Chihyun Park, Haijin Shin, Xu Yang, Kenji Kanazawa, Eunkyoung Kim

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The multi-color switching of electrofluorochromism was examined from the thin electrofluorochromic (EF) films of polyfluorene (PFO) and poly(propylenedioxythiophene-phenylene) (P(ProDOT-Ph)). The PFO and P(ProDOT-Ph) films showed vivid blue and yellow fluorescence, respectively, at neutral state but their emission was quenched upon application of oxidation potential leading to ion radical states. The fluorescence from the polymer films was reversibly switched to vivid color when the films were returned to their neutral states. The EF color switching ratio (rc1/c2) between the fluorescent state (c1) and dark (c2) state for the yellow color EF device with P(ProDOT-Ph) film was about four times higher than that of the PFO. Because the two polymer films have different colors and working potentials, a multi-color switching device was fabricated by coating the P(ProDOT-Ph) and PFO films onto working and counter electrodes, respectively. The multi-color EF device showed fluorescence switching from blue (B) to white (W) to yellow (Y), and vice versa, depending on the applied potential. The rc1/c2 for yellow (c1) and blue (c2) switching (Y/B) was larger (9.71) than those for Y/W and W/B. Moreover, the EF switching for Y/B in the multi-EF device was also very effective and showed the largest EF efficiency (EEF = 3.82 × 106) among the EF color switching.

Original languageEnglish
Pages (from-to)1808-1816
Number of pages9
JournalOptical Materials Express
Volume6
Issue number6
DOIs
Publication statusPublished - 2016 Jan 1

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Polymers
Fluorescence
Color
Polymer films
Ions
Thin films
Coatings
Oxidation
Electrodes

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials

Cite this

Lim, Hanwhuy ; Seo, Seogjae ; Park, Chihyun ; Shin, Haijin ; Yang, Xu ; Kanazawa, Kenji ; Kim, Eunkyoung. / Multi-color fluorescence switching with electrofluorochromic polymers. In: Optical Materials Express. 2016 ; Vol. 6, No. 6. pp. 1808-1816.
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abstract = "The multi-color switching of electrofluorochromism was examined from the thin electrofluorochromic (EF) films of polyfluorene (PFO) and poly(propylenedioxythiophene-phenylene) (P(ProDOT-Ph)). The PFO and P(ProDOT-Ph) films showed vivid blue and yellow fluorescence, respectively, at neutral state but their emission was quenched upon application of oxidation potential leading to ion radical states. The fluorescence from the polymer films was reversibly switched to vivid color when the films were returned to their neutral states. The EF color switching ratio (rc1/c2) between the fluorescent state (c1) and dark (c2) state for the yellow color EF device with P(ProDOT-Ph) film was about four times higher than that of the PFO. Because the two polymer films have different colors and working potentials, a multi-color switching device was fabricated by coating the P(ProDOT-Ph) and PFO films onto working and counter electrodes, respectively. The multi-color EF device showed fluorescence switching from blue (B) to white (W) to yellow (Y), and vice versa, depending on the applied potential. The rc1/c2 for yellow (c1) and blue (c2) switching (Y/B) was larger (9.71) than those for Y/W and W/B. Moreover, the EF switching for Y/B in the multi-EF device was also very effective and showed the largest EF efficiency (EEF = 3.82 × 106) among the EF color switching.",
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Lim, H, Seo, S, Park, C, Shin, H, Yang, X, Kanazawa, K & Kim, E 2016, 'Multi-color fluorescence switching with electrofluorochromic polymers', Optical Materials Express, vol. 6, no. 6, pp. 1808-1816. https://doi.org/10.1364/OME.6.001808

Multi-color fluorescence switching with electrofluorochromic polymers. / Lim, Hanwhuy; Seo, Seogjae; Park, Chihyun; Shin, Haijin; Yang, Xu; Kanazawa, Kenji; Kim, Eunkyoung.

In: Optical Materials Express, Vol. 6, No. 6, 01.01.2016, p. 1808-1816.

Research output: Contribution to journalArticle

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AU - Lim, Hanwhuy

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AU - Kim, Eunkyoung

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N2 - The multi-color switching of electrofluorochromism was examined from the thin electrofluorochromic (EF) films of polyfluorene (PFO) and poly(propylenedioxythiophene-phenylene) (P(ProDOT-Ph)). The PFO and P(ProDOT-Ph) films showed vivid blue and yellow fluorescence, respectively, at neutral state but their emission was quenched upon application of oxidation potential leading to ion radical states. The fluorescence from the polymer films was reversibly switched to vivid color when the films were returned to their neutral states. The EF color switching ratio (rc1/c2) between the fluorescent state (c1) and dark (c2) state for the yellow color EF device with P(ProDOT-Ph) film was about four times higher than that of the PFO. Because the two polymer films have different colors and working potentials, a multi-color switching device was fabricated by coating the P(ProDOT-Ph) and PFO films onto working and counter electrodes, respectively. The multi-color EF device showed fluorescence switching from blue (B) to white (W) to yellow (Y), and vice versa, depending on the applied potential. The rc1/c2 for yellow (c1) and blue (c2) switching (Y/B) was larger (9.71) than those for Y/W and W/B. Moreover, the EF switching for Y/B in the multi-EF device was also very effective and showed the largest EF efficiency (EEF = 3.82 × 106) among the EF color switching.

AB - The multi-color switching of electrofluorochromism was examined from the thin electrofluorochromic (EF) films of polyfluorene (PFO) and poly(propylenedioxythiophene-phenylene) (P(ProDOT-Ph)). The PFO and P(ProDOT-Ph) films showed vivid blue and yellow fluorescence, respectively, at neutral state but their emission was quenched upon application of oxidation potential leading to ion radical states. The fluorescence from the polymer films was reversibly switched to vivid color when the films were returned to their neutral states. The EF color switching ratio (rc1/c2) between the fluorescent state (c1) and dark (c2) state for the yellow color EF device with P(ProDOT-Ph) film was about four times higher than that of the PFO. Because the two polymer films have different colors and working potentials, a multi-color switching device was fabricated by coating the P(ProDOT-Ph) and PFO films onto working and counter electrodes, respectively. The multi-color EF device showed fluorescence switching from blue (B) to white (W) to yellow (Y), and vice versa, depending on the applied potential. The rc1/c2 for yellow (c1) and blue (c2) switching (Y/B) was larger (9.71) than those for Y/W and W/B. Moreover, the EF switching for Y/B in the multi-EF device was also very effective and showed the largest EF efficiency (EEF = 3.82 × 106) among the EF color switching.

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Lim H, Seo S, Park C, Shin H, Yang X, Kanazawa K et al. Multi-color fluorescence switching with electrofluorochromic polymers. Optical Materials Express. 2016 Jan 1;6(6):1808-1816. https://doi.org/10.1364/OME.6.001808