Multibranched and dendritic organic materials with high two-photon absorption activity

Seung Wan Kang, Joo Yeon Kim, Ran Hee Kim, Bong Keun So, Kwang Sup Lee, In Wook Hwang, Dongho Kim, Paul Fleitz, Hong Bo Sun, Satoshi Kawata

Research output: Contribution to journalConference article

2 Citations (Scopus)

Abstract

A three-dimensional micro-object was fabricated by two-photon initiated photopolymerization (TPIP) of soft-resin with the efficient two-photon absorbing multi-branched chromophore, EPS-3arm, which possesses high two-photon absorption cross-section of 5.21×10-47 cm4s/photons at 700 nm. The structural stability of the fabricated micro-objects could be achieved with aid of sol-gel process. The two-photon absorbing stilbazolium-cored dendrimer was also synthesized. The stillbazolium chromophore was covalently linked with the dendrimer chains so as to restrict free conformation motion. The hindered molecular twisting motion of the stilbazolium dye within the dendrimer is responsible for 5 to 16 times of enhancement in fluorescence emission along with the increased emission lifetime. The steady-state and time-resolved fluorescence emission study of the solid-state film indicate an efficient site-isolation and restriction of conformation motion of the active two-photon chromophore.

Original languageEnglish
Article number01
Pages (from-to)1-8
Number of pages8
JournalProceedings of SPIE - The International Society for Optical Engineering
Volume5621
DOIs
Publication statusPublished - 2004
EventOptical Materials in Defence Systems Technology - London, United Kingdom
Duration: 2004 Oct 252004 Oct 27

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

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    Kang, S. W., Kim, J. Y., Kim, R. H., So, B. K., Lee, K. S., Hwang, I. W., Kim, D., Fleitz, P., Sun, H. B., & Kawata, S. (2004). Multibranched and dendritic organic materials with high two-photon absorption activity. Proceedings of SPIE - The International Society for Optical Engineering, 5621, 1-8. [01]. https://doi.org/10.1117/12.582709