Multicore-shell nanofiber architecture of polyimide/polyvinylidene fluoride blend for thermal and long-term stability of lithium ion battery separator

Sejoon Park, Chung Woo Son, Sungho Lee, Dong Young Kim, Cheolmin Park, Kwang Sup Eom, Thomas F. Fuller, Han Ik Joh, Seong Mu Jo

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Li-ion battery, separator, multicoreshell structure, thermal stability, long-term stability. A nanofibrous membrane with multiple cores of polyimide (PI) in the shell of polyvinylidene fluoride (PVdF) was prepared using a facile one-pot electrospinning technique with a single nozzle. Unique multicore-shell (MCS) structure of the electrospun composite fibers was obtained, which resulted from electrospinning a phase-separated polymer composite solution. Multiple PI core fibrils with high molecular orientation were well-embedded across the cross-section and contributed remarkable thermal stabilities to the MCS membrane. Thus, no outbreaks were found in its dimension and ionic resistance up to 200 and 250 °C, respectively. Moreover, the MCS membrane (at ∼200 °C), as a lithium ion battery (LIB) separator, showed superior thermal and electrochemical stabilities compared with a widely used commercial separator (∼120 °C). The average capacity decay rate of LIB for 500 cycles was calculated to be approximately 0.030 mAh/g/cycle. This value demonstrated exceptional long-term stability compared with commercial LIBs and with two other types (single core-shell and co-electrospun separators incorporating with functionalized TiO2) of PI/PVdF composite separators. The proper architecture and synergy effects of multiple PI nanofibrils as a thermally stable polymer in the PVdF shell as electrolyte compatible polymers are responsible for the superior thermal performance and long-term stability of the LIB.

Original languageEnglish
Article number36977
JournalScientific Reports
Volume6
DOIs
Publication statusPublished - 2016 Nov 11

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Nanofibers
Separators
Polyimides
Polymers
Electrospinning
Membranes
Composite materials
Thermodynamic stability
Molecular orientation
Electrolytes
Nozzles
Hot Temperature
polyvinylidene fluoride
Lithium-ion batteries
Fibers

All Science Journal Classification (ASJC) codes

  • General

Cite this

Park, Sejoon ; Son, Chung Woo ; Lee, Sungho ; Kim, Dong Young ; Park, Cheolmin ; Eom, Kwang Sup ; Fuller, Thomas F. ; Joh, Han Ik ; Jo, Seong Mu. / Multicore-shell nanofiber architecture of polyimide/polyvinylidene fluoride blend for thermal and long-term stability of lithium ion battery separator. In: Scientific Reports. 2016 ; Vol. 6.
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Multicore-shell nanofiber architecture of polyimide/polyvinylidene fluoride blend for thermal and long-term stability of lithium ion battery separator. / Park, Sejoon; Son, Chung Woo; Lee, Sungho; Kim, Dong Young; Park, Cheolmin; Eom, Kwang Sup; Fuller, Thomas F.; Joh, Han Ik; Jo, Seong Mu.

In: Scientific Reports, Vol. 6, 36977, 11.11.2016.

Research output: Contribution to journalArticle

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AU - Park, Sejoon

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AU - Fuller, Thomas F.

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AB - Li-ion battery, separator, multicoreshell structure, thermal stability, long-term stability. A nanofibrous membrane with multiple cores of polyimide (PI) in the shell of polyvinylidene fluoride (PVdF) was prepared using a facile one-pot electrospinning technique with a single nozzle. Unique multicore-shell (MCS) structure of the electrospun composite fibers was obtained, which resulted from electrospinning a phase-separated polymer composite solution. Multiple PI core fibrils with high molecular orientation were well-embedded across the cross-section and contributed remarkable thermal stabilities to the MCS membrane. Thus, no outbreaks were found in its dimension and ionic resistance up to 200 and 250 °C, respectively. Moreover, the MCS membrane (at ∼200 °C), as a lithium ion battery (LIB) separator, showed superior thermal and electrochemical stabilities compared with a widely used commercial separator (∼120 °C). The average capacity decay rate of LIB for 500 cycles was calculated to be approximately 0.030 mAh/g/cycle. This value demonstrated exceptional long-term stability compared with commercial LIBs and with two other types (single core-shell and co-electrospun separators incorporating with functionalized TiO2) of PI/PVdF composite separators. The proper architecture and synergy effects of multiple PI nanofibrils as a thermally stable polymer in the PVdF shell as electrolyte compatible polymers are responsible for the superior thermal performance and long-term stability of the LIB.

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