Multifaceted [36]octaphyrin(1.1.1.1.1.1.1.1): Deprotonation-induced switching among nonaromatic, Möbius aromatic, and Hückel antiaromatic species

Won Young Cha; Takanori Soya; Takayuki Tanaka; Hirotaka Mori; Yongseok Hong; Sangsu Lee; Kyu Hyung Park; Atsuhiro Osuka; Dongho Kim

doi:10.1039/c6cc02051h

Multifaceted [36]octaphyrin(1.1.1.1.1.1.1.1): Deprotonation-induced switching among nonaromatic, Möbius aromatic, and Hückel antiaromatic species

Won Young Cha, Takanori Soya, Takayuki Tanaka, Hirotaka Mori, Yongseok Hong, Sangsu Lee, Kyu Hyung Park, Atsuhiro Osuka, Dongho Kim

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

Deprotonation of nonaromatic octakis-(pentafluorophenyl)-substituted [36]octaphyrin(1.1.1.1.1.1.1.1) with tetrabutylammonium fluoride (TBAF) afforded monoanionic twisted Möbius aromatic species and dianinonic square Hückel antiaromatic species, depending upon the amount of TBAF.

Original language	English
Pages (from-to)	6076-6078
Number of pages	3
Journal	Chemical Communications
Volume	52
Issue number	36
DOIs	https://doi.org/10.1039/c6cc02051h
Publication status	Published - 2016 May 4

Bibliographical note

Publisher Copyright:
© 2016 The Royal Society of Chemistry.

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c6cc02051h

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title = "Multifaceted [36]octaphyrin(1.1.1.1.1.1.1.1): Deprotonation-induced switching among nonaromatic, M{\"o}bius aromatic, and H{\"u}ckel antiaromatic species",

abstract = "Deprotonation of nonaromatic octakis-(pentafluorophenyl)-substituted [36]octaphyrin(1.1.1.1.1.1.1.1) with tetrabutylammonium fluoride (TBAF) afforded monoanionic twisted M{\"o}bius aromatic species and dianinonic square H{\"u}ckel antiaromatic species, depending upon the amount of TBAF.",

author = "Cha, {Won Young} and Takanori Soya and Takayuki Tanaka and Hirotaka Mori and Yongseok Hong and Sangsu Lee and Park, {Kyu Hyung} and Atsuhiro Osuka and Dongho Kim",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

month = may,

day = "4",

doi = "10.1039/c6cc02051h",

language = "English",

volume = "52",

pages = "6076--6078",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Multifaceted [36]octaphyrin(1.1.1.1.1.1.1.1)

T2 - Deprotonation-induced switching among nonaromatic, Möbius aromatic, and Hückel antiaromatic species

AU - Cha, Won Young

AU - Soya, Takanori

AU - Tanaka, Takayuki

AU - Mori, Hirotaka

AU - Hong, Yongseok

AU - Lee, Sangsu

AU - Park, Kyu Hyung

AU - Osuka, Atsuhiro

AU - Kim, Dongho

PY - 2016/5/4

Y1 - 2016/5/4

N2 - Deprotonation of nonaromatic octakis-(pentafluorophenyl)-substituted [36]octaphyrin(1.1.1.1.1.1.1.1) with tetrabutylammonium fluoride (TBAF) afforded monoanionic twisted Möbius aromatic species and dianinonic square Hückel antiaromatic species, depending upon the amount of TBAF.

AB - Deprotonation of nonaromatic octakis-(pentafluorophenyl)-substituted [36]octaphyrin(1.1.1.1.1.1.1.1) with tetrabutylammonium fluoride (TBAF) afforded monoanionic twisted Möbius aromatic species and dianinonic square Hückel antiaromatic species, depending upon the amount of TBAF.

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U2 - 10.1039/c6cc02051h

DO - 10.1039/c6cc02051h

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VL - 52

SP - 6076

EP - 6078

JO - Chemical Communications

JF - Chemical Communications

IS - 36

ER -

Multifaceted [36]octaphyrin(1.1.1.1.1.1.1.1): Deprotonation-induced switching among nonaromatic, Möbius aromatic, and Hückel antiaromatic species

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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