N-Methylaniline-induced Si-Si bond cleavages of perchlorooligosilanes

Sung Jin Park, Jong Min Choi, Hyeon Mo Cho, Cheol Hyun Kim, Myong Euy Lee

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

This study describes Si-Si bond cleavage of perchlorooligosilane using an amine. N-Methylaniline-induced Si-Si bond cleavage reactions of cyclic perchlorosilanes Si5Cl10 (1) and Si4Cl 8 (2), and acyclic perchlorosilanes Si5Cl12 (3) and Si2Cl6 (4) yielded the N,N-methylphenylamino- substituted monosilanes, (NMePh)3-nSiHCln (5; n = 2, 6; n = 1, 7; n = 0) and (NMePh)4-nSiCln (8; n = 2, 9; n = 3). Products and yields depended on the perchlorooligosilanes used. In addition, disproportionation between Si-N and Si-Cl bonds was observed in reactions of compounds 5 and 9.

Original languageEnglish
Pages (from-to)140-144
Number of pages5
JournalJournal of Organometallic Chemistry
Volume768
DOIs
Publication statusPublished - 2014 Oct 1

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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