Nanocomposite polymer electrolytes containing silica nanoparticles: Comparison between poly (ethylene glycol) and poly(ethylene oxide) dimethyl ether

Jung Tae Park, Kyung Ju Lee, Moon Sung Kang, Yong Soo Kang, Jong Hak Kim

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Nanocomposite polymer electrolytes consisting of low molecular weight polyethylene oxide) (PEO), iodine salt MI (M = K+, imidazolium +), and fumed silica nanoparticles have been prepared and characterized. The effect of terminal group in PEP, i.e., hydroxyl (-OH) and methyl (CH3) using poly(ethylene glycol) (PEG) and PEO dimethyl ether (PEODME), respectively, was investigated on the interactions, structures, and ionic conductivities of polymer electrolytes. Wide angle X-ray scattering (WAXS), differential scanning calorimetry (DSC), and complex viscosity measurements clearly showed that the gelation of PEG electrolytes occurred more effectively than that of PEODME electrolytes. It was attributed to the fact that the hydroxyl groups of PEG participated in the hydrogenbonding interaction between silica nanoparticles, and consequently helped to accelerate the gelation reaction, as confirmed by FTIR spectroscopy. Because of its interaction, the ionic conductivities of PEG electrolytes (maximum value ∼ 6.9 × 10-4 S/cm) were lower than that of PEODME electrolytes (2.3 × 10-3 S/cm).

Original languageEnglish
Pages (from-to)4083-4090
Number of pages8
JournalJournal of Applied Polymer Science
Volume106
Issue number6
DOIs
Publication statusPublished - 2007 Dec 15

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Polymers and Plastics
  • Materials Chemistry

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