TY - JOUR
T1 - Nanographite impurities dominate electrochemistry of carbon nanotubes
AU - Ambrosi, Adriano
AU - Pumera, Martin
N1 - Copyright:
Copyright 2011 Elsevier B.V., All rights reserved.
PY - 2010/9/24
Y1 - 2010/9/24
N2 - Junk does the work: The observed heterogeneous electron-transfer (HET) rate of multiwalled carbon nanotube (MWCNT) materials is comparable to that of graphite only because CNT materials contain large quantities of nanographite impurities. When pure CNTs are used, the observed HET rate is actually significantly lower than that of graphitic materials. In other words, most of the electrochemical activity of CNTs is due to the presence of the nanographite impurities contained within them. (Figure Presented)
AB - Junk does the work: The observed heterogeneous electron-transfer (HET) rate of multiwalled carbon nanotube (MWCNT) materials is comparable to that of graphite only because CNT materials contain large quantities of nanographite impurities. When pure CNTs are used, the observed HET rate is actually significantly lower than that of graphitic materials. In other words, most of the electrochemical activity of CNTs is due to the presence of the nanographite impurities contained within them. (Figure Presented)
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U2 - 10.1002/chem.201001584
DO - 10.1002/chem.201001584
M3 - Article
C2 - 20715215
AN - SCOPUS:77956546854
VL - 16
SP - 10946
EP - 10949
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 36
ER -