Nanohybrids of edible dyes intercalated in ZnAl layered double hydroxides

Jin Ho Choy, Yun Kyung Kim, You Hwan Son, Young Bin Choy, Jae Min Oh, Hyun Jung, Seong Ju Hwang

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Edible dyes such as Allura® Red AC (C18H14N2O8S22-), Sunset Yellow FCF (C16H10N2O7S22-), and Brilliant Blue FCF (C37H34N2O9S32-) were successfully intercalated into the gallery spaces of ZnAl layered double hydroxides (LDHs). Those organic-inorganic nanohybrids were synthesized by co-precipitating the aqueous solution of zinc nitrate and aluminum nitrate simultaneously in the presence of anionic dyes. From the X-ray diffraction and infrared spectroscopic analyses, we found that the dye molecules could be intercalated into hydroxide layers without any changes in their chemical and structural properties. The basal spacings were determined to be 24.0, 20.3, and 24.7 Å for Allura® Red AC, Sunset Yellow FCF, and Brilliant Blue FCF intercalated LDHs, respectively. According to the solid UV-vis spectroscopic analyses, the absorbance intensity of dye-intercalated LDHs was clearly enhanced with the band narrowing compared to those of the corresponding dye salts due to the charge transfer between the host lattice and spatially confined dye molecules.

Original languageEnglish
Pages (from-to)1547-1551
Number of pages5
JournalJournal of Physics and Chemistry of Solids
Volume69
Issue number5-6
DOIs
Publication statusPublished - 2008 May 1

Fingerprint

Hydroxides
hydroxides
Coloring Agents
Dyes
dyes
sunset
nitrates
Nitrates
alternating current
Molecules
chemical properties
Chemical properties
Charge transfer
Structural properties
molecules
Zinc
Salts
zinc
charge transfer
spacing

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Choy, Jin Ho ; Kim, Yun Kyung ; Son, You Hwan ; Choy, Young Bin ; Oh, Jae Min ; Jung, Hyun ; Hwang, Seong Ju. / Nanohybrids of edible dyes intercalated in ZnAl layered double hydroxides. In: Journal of Physics and Chemistry of Solids. 2008 ; Vol. 69, No. 5-6. pp. 1547-1551.
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abstract = "Edible dyes such as Allura{\circledR} Red AC (C18H14N2O8S22-), Sunset Yellow FCF (C16H10N2O7S22-), and Brilliant Blue FCF (C37H34N2O9S32-) were successfully intercalated into the gallery spaces of ZnAl layered double hydroxides (LDHs). Those organic-inorganic nanohybrids were synthesized by co-precipitating the aqueous solution of zinc nitrate and aluminum nitrate simultaneously in the presence of anionic dyes. From the X-ray diffraction and infrared spectroscopic analyses, we found that the dye molecules could be intercalated into hydroxide layers without any changes in their chemical and structural properties. The basal spacings were determined to be 24.0, 20.3, and 24.7 {\AA} for Allura{\circledR} Red AC, Sunset Yellow FCF, and Brilliant Blue FCF intercalated LDHs, respectively. According to the solid UV-vis spectroscopic analyses, the absorbance intensity of dye-intercalated LDHs was clearly enhanced with the band narrowing compared to those of the corresponding dye salts due to the charge transfer between the host lattice and spatially confined dye molecules.",
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Nanohybrids of edible dyes intercalated in ZnAl layered double hydroxides. / Choy, Jin Ho; Kim, Yun Kyung; Son, You Hwan; Choy, Young Bin; Oh, Jae Min; Jung, Hyun; Hwang, Seong Ju.

In: Journal of Physics and Chemistry of Solids, Vol. 69, No. 5-6, 01.05.2008, p. 1547-1551.

Research output: Contribution to journalArticle

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