Abstract
Conjugated rod molecules bearing flexible coil polymer moieties on both ends self-organize into one-dimensional (1D) or two-dimensional (2D) structures, and eventually into a three-dimensional (3D) tetragonal superlattice, depending on the number of monomeric units in the coils. The 3D ordered rods exhibit a highly extended fluorescence lifetime over the 1D or 2D arrays, making synthethic control of the rod-to-coil volume fraction a viable strategy to regulate photophysical properties.
| Original language | English |
|---|---|
| Pages (from-to) | 1363-1368 |
| Number of pages | 6 |
| Journal | Advanced Materials |
| Volume | 13 |
| Issue number | 18 |
| DOIs | |
| Publication status | Published - 2001 Sep 14 |
All Science Journal Classification (ASJC) codes
- Materials Science(all)
- Mechanics of Materials
- Mechanical Engineering
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Cite this
Lee, M., Kim, J. W., Hwang, I. W., Kim, Y. R., Oh, N. K., & Zin, W. C. (2001). Nanoscale organization of conjugated rods in rod-coil molecules. Advanced Materials, 13(18), 1363-1368. https://doi.org/10.1002/1521-4095(200109)13:18<1363::AID-ADMA1363>3.0.CO;2-I