Nanoscale organization of conjugated rods in rod-coil molecules

Myongsoo Lee; Jung Woo Kim; In Wook Hwang; Yong Rok Kim; Nam Keun Oh; Wang Cheol Zin

doi:10.1002/1521-4095(200109)13:18<1363::AID-ADMA1363>3.0.CO;2-I

Nanoscale organization of conjugated rods in rod-coil molecules

Myongsoo Lee, Jung Woo Kim, In Wook Hwang, Yong Rok Kim, Nam Keun Oh, Wang Cheol Zin

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

Conjugated rod molecules bearing flexible coil polymer moieties on both ends self-organize into one-dimensional (1D) or two-dimensional (2D) structures, and eventually into a three-dimensional (3D) tetragonal superlattice, depending on the number of monomeric units in the coils. The 3D ordered rods exhibit a highly extended fluorescence lifetime over the 1D or 2D arrays, making synthethic control of the rod-to-coil volume fraction a viable strategy to regulate photophysical properties.

Original language	English
Pages (from-to)	1363-1368
Number of pages	6
Journal	Advanced Materials
Volume	13
Issue number	18
DOIs	https://doi.org/10.1002/1521-4095(200109)13:18<1363::AID-ADMA1363>3.0.CO;2-I
Publication status	Published - 2001 Sep 14

All Science Journal Classification (ASJC) codes

Materials Science(all)
Mechanics of Materials
Mechanical Engineering

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10.1002/1521-4095(200109)13:18<1363::AID-ADMA1363>3.0.CO;2-I

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AU - Oh, Nam Keun

AU - Zin, Wang Cheol

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AB - Conjugated rod molecules bearing flexible coil polymer moieties on both ends self-organize into one-dimensional (1D) or two-dimensional (2D) structures, and eventually into a three-dimensional (3D) tetragonal superlattice, depending on the number of monomeric units in the coils. The 3D ordered rods exhibit a highly extended fluorescence lifetime over the 1D or 2D arrays, making synthethic control of the rod-to-coil volume fraction a viable strategy to regulate photophysical properties.

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Nanoscale organization of conjugated rods in rod-coil molecules

Abstract

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