New heteropolynuclear metallomesogens

Copper(II), palladium(II), nickel(II) and oxovanadium(IV) chelates with [3]ferrocenophane-containing Schiff's base and β-aminovinylketone

Hye Won Chae, Oleg N. Kadkin, Moon-Gun Choi

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

New mesogenic heteropolynuclear complexes of Cu(II), Pd(II), Ni(II) and VO(IV) with the [3]ferrocenophane-containing Schiff's base, and Cu(II) and Pd(II) complexes with the [3]ferrocenophane-containing β-aminovinylketone have been synthesised. The obtained heterometallic mesogenes are identified by elemental analysis, proton nuclear magnetic resonance, infrared and ultraviolet-visible spectroscopies. Liquid crystalline properties are studied by thermal polarising optical microscopy and differential scanning calorimetry techniques. Both ligands and heteropolynuclear complexes exhibit thermotropic nematic and smectic C mesophases in various temperature ranges except for the Ni(II) complex. Mesomorphism of the prepared complexes is correlated with the geometry of their central chelate core. Considerably broader mesophases and lower transition temperatures are achieved in the synthesised metallomesogens by using the alkylidene-bridged ferrocene as a building unit.

Original languageEnglish
Pages (from-to)53-60
Number of pages8
JournalLiquid Crystals
Volume36
Issue number1
DOIs
Publication statusPublished - 2009 Jan 1

Fingerprint

alkylidene
proton magnetic resonance
Schiff Bases
Palladium
Nickel
chelates
imines
palladium
Copper
heat measurement
transition temperature
Nuclear magnetic resonance
nickel
microscopy
copper
nuclear magnetic resonance
ligands
scanning
Ultraviolet visible spectroscopy
liquids

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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title = "New heteropolynuclear metallomesogens: Copper(II), palladium(II), nickel(II) and oxovanadium(IV) chelates with [3]ferrocenophane-containing Schiff's base and β-aminovinylketone",
abstract = "New mesogenic heteropolynuclear complexes of Cu(II), Pd(II), Ni(II) and VO(IV) with the [3]ferrocenophane-containing Schiff's base, and Cu(II) and Pd(II) complexes with the [3]ferrocenophane-containing β-aminovinylketone have been synthesised. The obtained heterometallic mesogenes are identified by elemental analysis, proton nuclear magnetic resonance, infrared and ultraviolet-visible spectroscopies. Liquid crystalline properties are studied by thermal polarising optical microscopy and differential scanning calorimetry techniques. Both ligands and heteropolynuclear complexes exhibit thermotropic nematic and smectic C mesophases in various temperature ranges except for the Ni(II) complex. Mesomorphism of the prepared complexes is correlated with the geometry of their central chelate core. Considerably broader mesophases and lower transition temperatures are achieved in the synthesised metallomesogens by using the alkylidene-bridged ferrocene as a building unit.",
author = "Chae, {Hye Won} and Kadkin, {Oleg N.} and Moon-Gun Choi",
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New heteropolynuclear metallomesogens : Copper(II), palladium(II), nickel(II) and oxovanadium(IV) chelates with [3]ferrocenophane-containing Schiff's base and β-aminovinylketone. / Chae, Hye Won; Kadkin, Oleg N.; Choi, Moon-Gun.

In: Liquid Crystals, Vol. 36, No. 1, 01.01.2009, p. 53-60.

Research output: Contribution to journalArticle

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