New Na-Ion Solid Electrolytes Na4−xSn1−xSbxS4 (0.02 ≤ x ≤ 0.33) for All-Solid-State Na-Ion Batteries

Jongwook W. Heo; Abhik Banerjee; Kern Ho Park; Yoon Seok Jung; Seung Tae Hong

doi:10.1002/aenm.201702716

New Na-Ion Solid Electrolytes Na₄₋_xSn₁₋_xSb_xS₄ (0.02 ≤ x ≤ 0.33) for All-Solid-State Na-Ion Batteries

Jongwook W. Heo, Abhik Banerjee, Kern Ho Park, Yoon Seok Jung, Seung Tae Hong

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

79 Citations (Scopus)

Abstract

Sulfide Na-ion solid electrolytes (SEs) are key to enable room-temperature operable all-solid-state Na-ion batteries that are attractive for large-scale energy storage applications. To date, few sulfide Na-ion SEs have been developed and most of the SEs developed contain P and suffer from poor chemical stability. Herein, discovery of a new structural class of tetragonal Na₄₋_xSn₁₋_xSb_xS₄ (0.02 ≤ x ≤ 0.33) with space group I4₁/acd is described. The evolution of a new phase, distinctly different from Na₄SnS₄ or Na₃SbS₄, allows fast ionic conduction in 3D pathways (0.2–0.5 mS cm⁻¹ at 30 °C). Moreover, their excellent air stability and reversible dissolution in water and precipitation are highlighted. Specifically, TiS₂/Na–Sn all-solid-state Na-ion batteries using Na_3.75Sn_0.75Sb_0.25S₄ demonstrates high capacity (201 mA h (g of TiS₂)⁻¹) with excellent reversibility.

Original language	English
Article number	1702716
Journal	Advanced Energy Materials
Volume	8
Issue number	11
DOIs	https://doi.org/10.1002/aenm.201702716
Publication status	Published - 2018 Apr 16

Bibliographical note

Funding Information:
J.W.H., A.B., and K.H.P. contributed equally to this work. This work was supported by Basic Science Research Program (No. NRF-2017M1A2A2044501) and by Leading Foreign Research Institute Recruitment Program (No. NRF-2017K1A4A3015437) through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT & Future Planning, and by the Materials and Components Technology Development Program of MOTIE/KEIT (10076731).

Publisher Copyright:
© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

All Science Journal Classification (ASJC) codes

Renewable Energy, Sustainability and the Environment
Materials Science(all)

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1002/aenm.201702716

Cite this

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title = "New Na-Ion Solid Electrolytes Na4−xSn1−xSbxS4 (0.02 ≤ x ≤ 0.33) for All-Solid-State Na-Ion Batteries",

abstract = "Sulfide Na-ion solid electrolytes (SEs) are key to enable room-temperature operable all-solid-state Na-ion batteries that are attractive for large-scale energy storage applications. To date, few sulfide Na-ion SEs have been developed and most of the SEs developed contain P and suffer from poor chemical stability. Herein, discovery of a new structural class of tetragonal Na4−xSn1−xSbxS4 (0.02 ≤ x ≤ 0.33) with space group I41/acd is described. The evolution of a new phase, distinctly different from Na4SnS4 or Na3SbS4, allows fast ionic conduction in 3D pathways (0.2–0.5 mS cm−1 at 30 °C). Moreover, their excellent air stability and reversible dissolution in water and precipitation are highlighted. Specifically, TiS2/Na–Sn all-solid-state Na-ion batteries using Na3.75Sn0.75Sb0.25S4 demonstrates high capacity (201 mA h (g of TiS2)−1) with excellent reversibility.",

author = "Heo, {Jongwook W.} and Abhik Banerjee and Park, {Kern Ho} and Jung, {Yoon Seok} and Hong, {Seung Tae}",

note = "Funding Information: J.W.H., A.B., and K.H.P. contributed equally to this work. This work was supported by Basic Science Research Program (No. NRF-2017M1A2A2044501) and by Leading Foreign Research Institute Recruitment Program (No. NRF-2017K1A4A3015437) through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT & Future Planning, and by the Materials and Components Technology Development Program of MOTIE/KEIT (10076731). Publisher Copyright: {\textcopyright} 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

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AU - Banerjee, Abhik

AU - Park, Kern Ho

AU - Jung, Yoon Seok

AU - Hong, Seung Tae

N1 - Funding Information: J.W.H., A.B., and K.H.P. contributed equally to this work. This work was supported by Basic Science Research Program (No. NRF-2017M1A2A2044501) and by Leading Foreign Research Institute Recruitment Program (No. NRF-2017K1A4A3015437) through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT & Future Planning, and by the Materials and Components Technology Development Program of MOTIE/KEIT (10076731). Publisher Copyright: © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

PY - 2018/4/16

Y1 - 2018/4/16

N2 - Sulfide Na-ion solid electrolytes (SEs) are key to enable room-temperature operable all-solid-state Na-ion batteries that are attractive for large-scale energy storage applications. To date, few sulfide Na-ion SEs have been developed and most of the SEs developed contain P and suffer from poor chemical stability. Herein, discovery of a new structural class of tetragonal Na4−xSn1−xSbxS4 (0.02 ≤ x ≤ 0.33) with space group I41/acd is described. The evolution of a new phase, distinctly different from Na4SnS4 or Na3SbS4, allows fast ionic conduction in 3D pathways (0.2–0.5 mS cm−1 at 30 °C). Moreover, their excellent air stability and reversible dissolution in water and precipitation are highlighted. Specifically, TiS2/Na–Sn all-solid-state Na-ion batteries using Na3.75Sn0.75Sb0.25S4 demonstrates high capacity (201 mA h (g of TiS2)−1) with excellent reversibility.

AB - Sulfide Na-ion solid electrolytes (SEs) are key to enable room-temperature operable all-solid-state Na-ion batteries that are attractive for large-scale energy storage applications. To date, few sulfide Na-ion SEs have been developed and most of the SEs developed contain P and suffer from poor chemical stability. Herein, discovery of a new structural class of tetragonal Na4−xSn1−xSbxS4 (0.02 ≤ x ≤ 0.33) with space group I41/acd is described. The evolution of a new phase, distinctly different from Na4SnS4 or Na3SbS4, allows fast ionic conduction in 3D pathways (0.2–0.5 mS cm−1 at 30 °C). Moreover, their excellent air stability and reversible dissolution in water and precipitation are highlighted. Specifically, TiS2/Na–Sn all-solid-state Na-ion batteries using Na3.75Sn0.75Sb0.25S4 demonstrates high capacity (201 mA h (g of TiS2)−1) with excellent reversibility.

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