Abstract
Acylferrocenes were synthesized by hydroiminoacylation of the ω-olefins 1-pentene (3a), vinylferrocene (3b) and but-3-enylferrocene (3c), with the ferrocenecarboxaldimine 2, prepared from ferrocenecarboxaldehyde (1) and 2-amino-3-picoline, under the action of Wilkinson's catalyst, followed by hydrolysis of the corresponding ketimines (5a, 5b and 5c). This hydroiminoacylation was used to incorporate the ferrocenyl group into phenyl-terminated poly-butadiene (PTPB, consisting of 27% vinyl and 73% internal olefin group). 74% hydroacylation of the vinyl group in 7 was accomplished in the first catalytic reaction and in 10 the second hydroacylation completed the conversion of the vinyl group into acylferrocene.
| Original language | English |
|---|---|
| Pages (from-to) | 193-198 |
| Number of pages | 6 |
| Journal | Journal of Organometallic Chemistry |
| Volume | 458 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - 1993 Oct 5 |
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All Science Journal Classification (ASJC) codes
- Biochemistry
- Chemical Engineering (miscellaneous)
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Materials Science (miscellaneous)
- Materials Chemistry
Cite this
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New synthesis of acylferrocene by hydroiminoacylation of the terminal olefin with ferrocenecarboxaldimine and application to polymer-supported acylferrocene. / Chul-Ho, Jun; Jung-Bu, Kang; Jin-Yong, Kim.
In: Journal of Organometallic Chemistry, Vol. 458, No. 1-2, 05.10.1993, p. 193-198.Research output: Contribution to journal › Article
TY - JOUR
T1 - New synthesis of acylferrocene by hydroiminoacylation of the terminal olefin with ferrocenecarboxaldimine and application to polymer-supported acylferrocene
AU - Chul-Ho, Jun
AU - Jung-Bu, Kang
AU - Jin-Yong, Kim
PY - 1993/10/5
Y1 - 1993/10/5
N2 - Acylferrocenes were synthesized by hydroiminoacylation of the ω-olefins 1-pentene (3a), vinylferrocene (3b) and but-3-enylferrocene (3c), with the ferrocenecarboxaldimine 2, prepared from ferrocenecarboxaldehyde (1) and 2-amino-3-picoline, under the action of Wilkinson's catalyst, followed by hydrolysis of the corresponding ketimines (5a, 5b and 5c). This hydroiminoacylation was used to incorporate the ferrocenyl group into phenyl-terminated poly-butadiene (PTPB, consisting of 27% vinyl and 73% internal olefin group). 74% hydroacylation of the vinyl group in 7 was accomplished in the first catalytic reaction and in 10 the second hydroacylation completed the conversion of the vinyl group into acylferrocene.
AB - Acylferrocenes were synthesized by hydroiminoacylation of the ω-olefins 1-pentene (3a), vinylferrocene (3b) and but-3-enylferrocene (3c), with the ferrocenecarboxaldimine 2, prepared from ferrocenecarboxaldehyde (1) and 2-amino-3-picoline, under the action of Wilkinson's catalyst, followed by hydrolysis of the corresponding ketimines (5a, 5b and 5c). This hydroiminoacylation was used to incorporate the ferrocenyl group into phenyl-terminated poly-butadiene (PTPB, consisting of 27% vinyl and 73% internal olefin group). 74% hydroacylation of the vinyl group in 7 was accomplished in the first catalytic reaction and in 10 the second hydroacylation completed the conversion of the vinyl group into acylferrocene.
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U2 - 10.1016/0022-328X(93)80473-O
DO - 10.1016/0022-328X(93)80473-O
M3 - Article
VL - 458
SP - 193
EP - 198
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 1-2
ER -