TY - JOUR
T1 - New synthesis of acylferrocene by hydroiminoacylation of the terminal olefin with ferrocenecarboxaldimine and application to polymer-supported acylferrocene
AU - Chul-Ho, Jun
AU - Jung-Bu, Kang
AU - Jin-Yong, Kim
N1 - Copyright:
Copyright 2014 Elsevier B.V., All rights reserved.
PY - 1993/10/5
Y1 - 1993/10/5
N2 - Acylferrocenes were synthesized by hydroiminoacylation of the ω-olefins 1-pentene (3a), vinylferrocene (3b) and but-3-enylferrocene (3c), with the ferrocenecarboxaldimine 2, prepared from ferrocenecarboxaldehyde (1) and 2-amino-3-picoline, under the action of Wilkinson's catalyst, followed by hydrolysis of the corresponding ketimines (5a, 5b and 5c). This hydroiminoacylation was used to incorporate the ferrocenyl group into phenyl-terminated poly-butadiene (PTPB, consisting of 27% vinyl and 73% internal olefin group). 74% hydroacylation of the vinyl group in 7 was accomplished in the first catalytic reaction and in 10 the second hydroacylation completed the conversion of the vinyl group into acylferrocene.
AB - Acylferrocenes were synthesized by hydroiminoacylation of the ω-olefins 1-pentene (3a), vinylferrocene (3b) and but-3-enylferrocene (3c), with the ferrocenecarboxaldimine 2, prepared from ferrocenecarboxaldehyde (1) and 2-amino-3-picoline, under the action of Wilkinson's catalyst, followed by hydrolysis of the corresponding ketimines (5a, 5b and 5c). This hydroiminoacylation was used to incorporate the ferrocenyl group into phenyl-terminated poly-butadiene (PTPB, consisting of 27% vinyl and 73% internal olefin group). 74% hydroacylation of the vinyl group in 7 was accomplished in the first catalytic reaction and in 10 the second hydroacylation completed the conversion of the vinyl group into acylferrocene.
UR - http://www.scopus.com/inward/record.url?scp=43949164690&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=43949164690&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(93)80473-O
DO - 10.1016/0022-328X(93)80473-O
M3 - Article
AN - SCOPUS:43949164690
VL - 458
SP - 193
EP - 198
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 1-2
ER -