New synthetic routes for silaheterocycles: Reactions of a chlorosilylenoid with aldehydes

Young Mook Lim, Chang Hee Park, Soo Jin Yoon, Hyeon Mo Cho, Myong Euy Lee, Kyoung Koo Baeck

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

(Tsi)chlorosilylenoid [Tsi = C(SiMe3)3] reacted with acetaldehyde and benzaldehyde to give 2,4dioxasilolane and 2,5-dioxasilolane, respectively. The direct addition of an aldehyde to a silaoxirane intermediate is proposed as a plausible mechanism based on a theoretical study. These results show a new synthetic application of the chlorosilylenoid and a new route for the synthesis of silaheterocycles.

Original languageEnglish
Pages (from-to)1355-1361
Number of pages7
JournalOrganometallics
Volume29
Issue number6
DOIs
Publication statusPublished - 2010 Mar 22

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Acetaldehyde
acetaldehyde
aldehydes
Aldehydes
routes
synthesis
benzaldehyde

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Lim, Young Mook ; Park, Chang Hee ; Yoon, Soo Jin ; Cho, Hyeon Mo ; Lee, Myong Euy ; Baeck, Kyoung Koo. / New synthetic routes for silaheterocycles : Reactions of a chlorosilylenoid with aldehydes. In: Organometallics. 2010 ; Vol. 29, No. 6. pp. 1355-1361.
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New synthetic routes for silaheterocycles : Reactions of a chlorosilylenoid with aldehydes. / Lim, Young Mook; Park, Chang Hee; Yoon, Soo Jin; Cho, Hyeon Mo; Lee, Myong Euy; Baeck, Kyoung Koo.

In: Organometallics, Vol. 29, No. 6, 22.03.2010, p. 1355-1361.

Research output: Contribution to journalArticle

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AU - Lim, Young Mook

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AU - Lee, Myong Euy

AU - Baeck, Kyoung Koo

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