New synthetic routes for silaheterocycles: Reactions of a chlorosilylenoid with aldehydes

Young Mook Lim, Chang Hee Park, Soo Jin Yoon, Hyeon Mo Cho, Myong Euy Lee, Kyoung Koo Baeck

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

(Tsi)chlorosilylenoid [Tsi = C(SiMe3)3] reacted with acetaldehyde and benzaldehyde to give 2,4dioxasilolane and 2,5-dioxasilolane, respectively. The direct addition of an aldehyde to a silaoxirane intermediate is proposed as a plausible mechanism based on a theoretical study. These results show a new synthetic application of the chlorosilylenoid and a new route for the synthesis of silaheterocycles.

Original languageEnglish
Pages (from-to)1355-1361
Number of pages7
JournalOrganometallics
Volume29
Issue number6
DOIs
Publication statusPublished - 2010 Mar 22

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All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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