Nitrogen-doped carbon catalysts derived from ionic liquids in the presence of transition metals for the oxygen reduction reaction

Katie H. Lim, Hansung Kim

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Nitrogen-doped carbon catalysts for the oxygen reduction reaction (ORR) were synthesized by the pyrolysis of ionic liquids (IL), which are precursors of both nitrogen and carbon, using a silica hard template in the presence of a transition metal. From the linear sweep voltammogram recorded in an acidic solution, the ORR activity of the nitrogen-doped carbon catalysts increased significantly after the addition of the transition metal during the pyrolysis of the IL. From XPS-N 1s analysis, the introduction of the transition metal positively contributes to the formation of graphitic-N, which is known to be an active site for the ORR. The results of XPS-C 1s suggest a strong correlation between the sp2-carbon network and the ORR activity. Co is a more effective metal compared to Ni due to the creation of a higher degree of sp2-carbon networks for fast electron transfer during the ORR. Based on the quantitative analysis of the experimental results, the IL is a promising precursor for nitrogen-doped carbon catalysts, and the addition of a transition metal is essential for improved activity of the ORR.

Original languageEnglish
Pages (from-to)355-360
Number of pages6
JournalApplied Catalysis B: Environmental
Volume158-159
DOIs
Publication statusPublished - 2014 Oct

Fingerprint

Ionic Liquids
transition element
Ionic liquids
Transition metals
Nitrogen
Carbon
catalyst
Oxygen
oxygen
Catalysts
nitrogen
carbon
pyrolysis
X-ray spectroscopy
Pyrolysis
X ray photoelectron spectroscopy
Silicon Dioxide
quantitative analysis
ionic liquid
silica

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Environmental Science(all)
  • Process Chemistry and Technology

Cite this

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abstract = "Nitrogen-doped carbon catalysts for the oxygen reduction reaction (ORR) were synthesized by the pyrolysis of ionic liquids (IL), which are precursors of both nitrogen and carbon, using a silica hard template in the presence of a transition metal. From the linear sweep voltammogram recorded in an acidic solution, the ORR activity of the nitrogen-doped carbon catalysts increased significantly after the addition of the transition metal during the pyrolysis of the IL. From XPS-N 1s analysis, the introduction of the transition metal positively contributes to the formation of graphitic-N, which is known to be an active site for the ORR. The results of XPS-C 1s suggest a strong correlation between the sp2-carbon network and the ORR activity. Co is a more effective metal compared to Ni due to the creation of a higher degree of sp2-carbon networks for fast electron transfer during the ORR. Based on the quantitative analysis of the experimental results, the IL is a promising precursor for nitrogen-doped carbon catalysts, and the addition of a transition metal is essential for improved activity of the ORR.",
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AU - Lim, Katie H.

AU - Kim, Hansung

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N2 - Nitrogen-doped carbon catalysts for the oxygen reduction reaction (ORR) were synthesized by the pyrolysis of ionic liquids (IL), which are precursors of both nitrogen and carbon, using a silica hard template in the presence of a transition metal. From the linear sweep voltammogram recorded in an acidic solution, the ORR activity of the nitrogen-doped carbon catalysts increased significantly after the addition of the transition metal during the pyrolysis of the IL. From XPS-N 1s analysis, the introduction of the transition metal positively contributes to the formation of graphitic-N, which is known to be an active site for the ORR. The results of XPS-C 1s suggest a strong correlation between the sp2-carbon network and the ORR activity. Co is a more effective metal compared to Ni due to the creation of a higher degree of sp2-carbon networks for fast electron transfer during the ORR. Based on the quantitative analysis of the experimental results, the IL is a promising precursor for nitrogen-doped carbon catalysts, and the addition of a transition metal is essential for improved activity of the ORR.

AB - Nitrogen-doped carbon catalysts for the oxygen reduction reaction (ORR) were synthesized by the pyrolysis of ionic liquids (IL), which are precursors of both nitrogen and carbon, using a silica hard template in the presence of a transition metal. From the linear sweep voltammogram recorded in an acidic solution, the ORR activity of the nitrogen-doped carbon catalysts increased significantly after the addition of the transition metal during the pyrolysis of the IL. From XPS-N 1s analysis, the introduction of the transition metal positively contributes to the formation of graphitic-N, which is known to be an active site for the ORR. The results of XPS-C 1s suggest a strong correlation between the sp2-carbon network and the ORR activity. Co is a more effective metal compared to Ni due to the creation of a higher degree of sp2-carbon networks for fast electron transfer during the ORR. Based on the quantitative analysis of the experimental results, the IL is a promising precursor for nitrogen-doped carbon catalysts, and the addition of a transition metal is essential for improved activity of the ORR.

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